CAS: 2445-76-3; Hexyl Propionate

相似化合物

52663-48-6 6221-93-8 110-39-4

上下游产品

CAS号925-78-0 3-壬酮 | CAS号105-37-3 丙酸乙酯 | CAS号111-27-3 正己醇 | CAS号2499-95-8 丙烯酸己酯 | CAS号123-62-6 丙酸酐 | CAS号6151-90-2 dihexoxy(oxo)ph... | CAS号557-28-8 丙酸锌 | CAS号4212-43-5 peroxypropionic acid

3-壬酮置于phosphite Dehydrogenase,Cyanidioschyzon Merolae Strain 10D (Nies-1332) Baeyer-Villiger Monooxygenase,磷酸肌酸,还原型辅酶ii(Nadph)四钠盐体系中,用 1,4-二氧六环 用作溶剂,化学反应生成丙酸己酯
参考文献:从光合真核生物中发现拜尔-维利格单加氧酶
标题:从光合真核生物中发现拜尔-维利格单加氧酶
摘要:拜耳－维利格单加氧酶是有吸引力的"绿色"催化剂,能够从酮开始生产手性酯或内酯.它们可以充当过氧酸的天然等同物,过氧酸是有机合成反应中传统使用的催化剂,包括cc键的断裂和氧原子的同时插入.
Doi:10.1016/j.Molcatb.2013.10.006

专利信息

专利号:US-7078574-B2
优先权日:2001-04-21
标题 :Method for the intrinsically safe handling of 3-chloropropyne
发明人：STAMM ARMIN; KNEUPER HEINZ-JOSEF; RITTINGER STEFAN; DRANSFELD PETER; SCHILDBERG HANS-PETER; HEILIG MANFRED; WEBER THEODOR
权利人:BASF AG
摘要:A method is provided for the intrinsically safe handling of 3-chloropropyne in the presence of a diluent with a boiling point ranging from −50° C. (223 K) to 200° C. (473 K) under atmospheric pressure, wherein the concentration of 3-chloropropyne in the liquid phase and in the gas phase is kept below the concentrations capable of deflagration by means of the type and amount of the diluent, the temperature and the total system pressure, together with the use of a 3-chloropropyne prepared, stored or transported in this way in the synthesis of dyestuffs, pharmaceutical and agricultural active ingredients, electroplating auxiliaries, disinfectants, steroids and growth hormones.

专利号:US-5278337-A
优先权日:1992-10-14
标 题:Enantiomeric resolution of aryl-substituted aliphatic carboxylic acids
发明人：MANIMARAN THANIKAVELU; STAHLY G PATRICK; HERNDON JR R CARL
权利人:ETHYL CORP
摘要:A process for obtaining a substantially pure enantiomer of an aryl-substituted aliphatic carboxylic acid is described. The process utilizes first an enantiomerically enriched mixture the of aryl-substituted aliphatic carboxylic acid obtained from kinetic resolution, diastereomeric crystallization or asymmetric synthesis processes. This enriched mixture is reacted with a base producing a salt that has the following properties: n 1) has at least one eutectic point; n 2) a composition that is not at the eutectic point; and n 3) a eutectic composition that is closer to the racemic composition than is the eutectic composition of said aryl-substituted carboxylic acid. n Substantially pure, enantiomeric salt is separated, leaving a mother liquor comprising the solvent and aryl-substituted aliphatic carboxylic acid enriched in the other enantiomer.

专利号:US-5248813-A
优先权日:1992-10-14
标题:Enantiomeric resolution
发明人：MANIMARAN THANIKAVELU; STAHLY G PATRICK; HERNDON JR R CARL
权利人:ETHYL CORP
摘要:A process for obtaining a substantially pure enantiomer of an aryl-substituted aliphatic carboxylic acid is described. The process utilizes first an enantiomerically enriched mixture the of aryl-substituted aliphatic carboxylic acid obtained from kinetic resolution, diastereomeric crystallization or asymmetric synthesis processes. This enriched mixture is reacted with a base producing a salt that has the following properties: n (1) has at least one eutectic point; n (2) a composition that is not at the eutectic point; and n (3) a eutectic composition that is closer to the racemic composition than is the eutectic composition of said aryl-substituted carboxylic acid. n Substantially pure, enantiomeric salt is separated, leaving a mother liquor comprising the solvent and aryl-substituted aliphatic carboxylic acid enriched in the other enantiomer.

专利号:WO-2023240156-A1
优先权日:2022-06-08
标 题 :Ionizable cationic lipids and lipid nanoparticles, and methods of synthesis and use thereof

专利号:TW-I277624-B
优先权日:2002-02-01
标 题 :Oligomeric chain extenders for processing, post-processing and recycling of condensation polymers, synthesis, compositions and applications

专利号:US-5442117-A
优先权日:1993-12-13
标题 :Enantiomeric resolution
发明人：STAHLY G PATRICK; MANIMARAN THANIKAVELU
权利人:ALBEMARLE CORP
摘要:A process for obtaining a substantially pure enantiomer of an hydrocarbyl amine is described. The process utilizes first an enantiomerically enriched mixture the of hydrocarbyl amine obtained from kinetic resolution, diastereomeric crystallization or asymmetric synthesis processes. This enriched mixture is reacted with an inorganic acid producing a salt that has the following properties: n 1) has at least one eutectic point; n 2) a composition that is not at the eutectic point; and n 3) a eutectic composition that is closer to the racemic n composition than is the eutectic composition of said n hydrocarbyl, or be a solid where the salt is a liquid. A substantially pure, enantiomeric salt is separated, leaving a mother liquor comprising the solvent and the hydrocarbyl amine enriched in the other enantiomer.