📜1-[3-(α-D-Glucopyranosyloxy)-2-Furanyl]-1-Ethanone 反应生成1-(3-羟基-2-呋喃基)乙酮 参考文献:Isolation Of 3-O-α-D-Gluco-And 3-O-β-D-Galacto-Pyranosyloxy-2-Furyl Methyl Ketones From Nonenzymic Browning Of Maltose And Lactose With Secondary Amino Acids 标题:Isolation Of 3-O-α-D-Gluco-And 3-O-β-D-Galacto-Pyranosyloxy-2-Furyl Methyl Ketones From Nonenzymic Browning Of Maltose And Lactose With Secondary Amino Acids 摘要: Doi:10.1016/0008-6215(83)88160-9
专利号:US-2006030625-A1 优先权日:2004-08-06 标 题 :Dietary neurotransmitter precursors for balanced synthesis of neurotransmitters 发明人:HART CHERYLE RAM; GROSSMAN RONALD S; RAM HERBERT 权利人:HART CHERYLE RAM; GROSSMAN RONALD S; RAM HERBERT 摘要:Dietary supplements for treating a neurotransmitter deficiency include one or more precursors of the deficient neurotransmitter and a cofactor for activating in vivo enzymatic synthesis of the deficient neurotransmitter. The dietary supplements can also include an appropriate neurotransmitter, such as an amino acid. When administered through the oral mucosa, increases in levels of the deficient neurotransmitters and relief from deficiency symptoms are obtained.
专利号:US-2017204442-A1 优先权日:2014-05-29 标题 :Enzymatic synthesis of soluble glucan fiber 发明人:DICOSIMO ROBERT; CHENG QIONG; ELIOT ANDREW C; OUWEHAND ARTHUR; PAYNE MARK S; YOU ZHENG 权利人:DU PONT 摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-11692058-B2 优先权日:2021-02-26 标题:Synthesis of functional polyurethanes and polyesters from biomass-derived monomers 发明人:CHANG HOCHAN; HUBER GEORGE W; DUMESIC JAMES A 权利人:WISCONSIN ALUMNI RES FOUND 摘要:A method of making polyesters and polyurethanes from biomass-derived polyols. The polyol is biomass-derived and has the structure:wherein dashed bonds are single or double bonds and R is selected from the group consisting of —OH and â• O. Polyurethanes are made by reacting the polyol with a diisocyanate. Polyesters are made by reacting the polyol with a dicarboxylic acid.
专利号:US-9090550-B2 优先权日:2010-07-30 标 题:Microwave assisted synthesis of dehydrated sugar derivatives hydroxymethylfurfural, levulinic acid, anhydrosugar alcohols, and ethers thereof 发明人:HOWARD STEPHEN J; SANBORN ALEXANDRA J 权利人:HOWARD STEPHEN J; SANBORN ALEXANDRA J; ARCHER DANIELS MIDLAND CO 摘要:Methods for the production of dehydrated sugars and derivatives of dehydrated sugars using microwave (MW) irradiation and methods of purifying the same are described. The dehydrated sugars derivatives include 5-hydroxymethyl-2-furfural (HMF) and anhydrosugar alcohols such as sorbitans and isosorbide. The derivatives include HMF ethers, levulinic acid esters, and ether derivatives of the anhydrosugar alcohols. The described methods require lower reaction temperatures and shorter reaction times than similar non microwave mediated reactions known in the art. Typical reaction conditions are 120-210° C., and typical reaction times are 30 minutes or less.
专利号:US-2023295102-A1 优先权日:2020-08-11 标 题 :A process for preparation of 2, 5-furan dicarboxylic acid from 5-hydroxymethyl furfural 发明人:DHEPE PARESH LAXMIKANT; SONONE KALYANI GAJANANRAO; LOKHANDE PRIYA LAXMANRAO 权利人:COUNCIL SCIENT IND RES 摘要:The present invention provides a process for the synthesis of furan dicarboxylic acid (FDCA) from glucose or crude hydroxy methyl furfural (HMF) using mixed metal oxides catalyst. The present invention further provides a process for preparation of the mixed metal oxides catalyst.
专利号:US-2017198323-A1 优先权日:2014-05-29 标题:Enzymatic synthesis of soluble glucan fiber 发明人:CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; PAYNE MARK S; PRASAD JAHNAVI CHANDRA 权利人:DU PONT 摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
1: Heine KB, Clegg JK, Heine A, Gloe K, Gloe K, Henle T, Bernhard G, Cai ZL, Reimers JR, Lindoy LF, Lach J, Kersting B. Complexation, computational, magnetic, and structural studies of the Maillard reaction product isomaltol including investigation of an uncommon π interaction with copper(II). Inorg Chem. 2011 Feb 21;50(4):1498-505. doi: 10.1021/ic102117d. Epub 2011 Jan 26. Epub 2006 Jan 20. doi: 10.1016/j.foodchem.2015.03.097. Epub 2015 Mar 28. German. German. German.
合成参考文献
参考文献:10.1021/ic025612u 摘要:Cecconi F, Ghilardi CA, Ienco A, Mariani P, Mealli C, Midollini S, Orlandini A, Vacca A. Different complexation properties of some hydroxy keto heterocycles toward beryllium(II) in aqueous solutions: experimental and theoretical studies. Inorg Chem. 2002 Jul 29;41(15):4006–17. doi: 10.1021/ic025612u.