CAS: 151139-88-7; (S)-4-Amino-2,2-Dimethylpentanedioic Acid
该化合物是一种非蛋白性氨酸,其独特结构特征包括四碳附着的两个甲基组,其中含有谷状酸脊柱,与标准的氨基酸相比,这种改变会影响其溶性与反应性.该化合物一般是白色晶状固体,在水中可溶解,适合各种生化应用.它经常在研究环境中使用,特别是在与...
- 英文名称(S)-4-Amino-2,2-Dimethylpentanedioic Acid
- 中文名称(S)-4-氨基-2,2-二甲基戊二酸
- IUPAC名称(S)-4-amino-2,2-dimethylpentanedioic acid
- 其它别名4,4-Dimethyl-L-Glutamic Acid; L-Glutamic Acid, 4,4-Dimethyl-; (4S)-4-Amino-2,2-Dimethylpentanedioicaci; 4-Dimethyl-L-Glutamic Acid Usp/ep/bp
- CAS编号151139-88-7
- 分子式:C7H13NO4分子量:175.18
- 产品CID: 736288
- 产品分类有机原料→分子砌块→脂肪链类化合物
相似化合物
31137-74-3 57224-50-7 106247-35-2物理性质
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上下游产品
2-oxo-4,4-dimethylglutaric acid 1-tert-butyl O2-methyl (2S)-4,4-dimethyl-5-oxopyrrolidine-1,2-dicarboxylateO1-tert-butyl O2-methyl (2S)-4,4-dimethyl-5-oxopyrrolidine-1,2-dicarboxylate 1-tert-butyl 2-ethyl (2S)4,4-dimethyl-5-oxopyrrolidine-1,2-dicarboxylate (S)-1-tert-butoxycarbonyl-5-methoxycarbonyl-pyrrolidin-2-one合成工艺路线路线简述
📜2-甲基1-(2-甲基-2-丙基)4,4-二甲基-5-氧代-1,2-吡咯烷二羧酸酯置于lithium Hydroxide,三氟乙酸体系中,用 四氢呋喃,二氯甲烷,水 用作溶剂,化学反应生成4-二甲基-L-谷氨酸
参考文献:A Concise Synthesis Of (2 S,4 R )-And (2 S,4 S )-4-Methylglutamic Acid
标题:A Concise Synthesis Of (2 S,4 R )-And (2 S,4 S )-4-Methylglutamic Acid
摘要:A Concise,Multi-Gram Scale Method For Producing The Bioactive And Enantiomerically Pure Epimers,(2S,4R)-And (2S,4S)-Glutamic Acids,In A Single Synthetic Scheme Is Described. (C) 2003 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0040-4039(03)00429-5
海关参考信息
- 2905121000-正丙醇
2912110000-甲醛
2912120000-乙醛
2915110000-甲酸 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
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主要参考文献
参考标题:Synthesis Of 4,4-Disubstituted作者:Virgil Hélaine,Joël Rossi,Thierry Gefflaut,Sébastien Alaux,Jean Bolte |发布日期:2001.8
摘要:The Syntheses Of Optically Pure 4,4-Dimethyl-L-Glutamic Acid As Well As (2S,4R)- And (2S,4S)-4-Hydroxy-4-Methylglutamic Acids Have Been Achieved By Transamination Of The Corresponding 2-Oxo-4,4-Dimethyl- And Rac-2-Oxo-4-Hydroxy-4-Methylglutaric Acids Using Glutamic Oxalacetic Transaminase (Got).
合成参考文献
参考DOI号:3.0.CO;2-6">10.1002/1615-4169(200108)343:6/7<692::AID-ADSC692>3.0.CO;2-6
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