CAS: 14024-58-9; Manganese(Ii) Bis(Acetylacetonate)

该化合物是锰的一种协调化合物,其中锰离子处于+2氧化状态,与丙烯酮(又称2,4-pentanedione)相混合,该化合物一般是一种红褐色固体,在乙醇和乙酮等有机溶剂中可溶解,但在水中可溶解. 锰(II) 以其在各种有机反应(包括聚合和氧化过程)中作为催化剂的作用而著称.由于锰离子在锰内存在未浸泡的电,该化合物具有致磁性.该化合物在正常条件下相对稳定,但应当小心处理,因为锰化合物在高浓度中可能有毒.此外,它被用于制成含锰材料,并作为其他锰复合材料合成的前体.

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sodium (Z)-4-oxopent-2-en-2-olate manganese(ll) chloride acetylacetonetrans-[bis(2-salicyloylhydrazonato-1,3-dithiolane)bis(pyridine)manganese(II)] 3,5-dimethyl-1-phenyl-1H-pyrazole 3-((phenylamino)methylene)pentane-2,4-dione

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    专利号:US-2024075466-A1
    优先权日:2021-04-09
    标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
    发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
    权利人:UMICORE AG & CO KG
    摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

    专利号:WO-2020248278-A1
    优先权日:2019-06-14
    标题:Method for continuous synthesis of substituted benzoic-acid organic substance
    发明人:HONG HAO; ZHANG ENXUAN; LU JIANGPING; LIU ZHIQING; LI CHAO; TANG YANG
    权利人:JINLIN ASYMCHEM LABORATORIES CO LTD
    摘要:The present invention provides a method for the continuous synthesis of a substituted benzoic-acid organic substance. The continuous synthesis method comprises: in the presence of catalyst and organic solvent, the organic matter represented by formula (I) and oxygen are continuously inputted to a continuous reaction apparatus for continuous oxidation reaction to obtain a substituted benzoic-acid organic substance, which is discharged continuously, the substituted benzoic-acid organic substance having the structure represented by formula (II). Oxygen is a green reagent and is inexpensive and readily available; a large amount of wastewater, waste gas, and solid waste is not generated after the reaction, and the system is easy to handle. The use of a continuous reaction operation can reduce the risk of flash distillation and explosion of solvent due to a high concentration of oxygen in a batch reaction. Under the same oxidation conditions, the continuous preparation process can reduce the escape of oxygen, greatly increasing the oxygen utilization rate and also simplifying the operation, improving the safety of the reaction and the yield of the substituted benzoic-acid organic substance.

    专利号:US-10053406-B2
    优先权日:2015-10-23
    标题 :Synthesis of honokiol
    发明人:JARACZ STANISLAV; KOZLOWSKI MARISA; EUN LEE YOUNG; KIM SUN MIN
    权利人:COLGATE PALMOLIVE CO; UNIV PENNSYLVANIA
    摘要:Disclosed herein are improved methods for the synthesis of honokiol, as well as methods for the synthesis of 3,3′-di-tert-butyl-5,5′-dimethyl-[1,1′-biphenyl]-2,4′-diol, 3′,5-dimethyl-[1,1′-biphenyl]-2,4′-diol, and 2,4′-dimethoxy-3′,5-dimethyl-1,1′-biphenyl, 3,3′,5,5′-tetra-tert-butyl-[1,1′-biphenyl]-2,4′-diol, and certain tetrasubstituted bisphenols, and uses therefor.

    专利号:US-2024368099-A1
    优先权日:2022-01-18
    标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
    发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS
    权利人:HENKEL AG & CO KGAA
    摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

    专利号:US-2025197439-A1
    优先权日:2022-03-18
    标 题:Decarboxylative acetoxylation using mn(ii) or mn(iii) reagent for synthesis of 4'-acetoxy-nucleoside and use thereof for synthesis of corresponding 4'-(dimethoxyphosphoryl)methoxy-nucleotide
    发明人:VAGLE KURT EDRIC; BHADURI SAYANTAN; YANG GUOHAN
    权利人:DICERNA PHARMACEUTICALS INC
    摘要:The present invention relates to the preparation of nucleic acids, nucleosides, nucleotides, and analogues thereof useful as potent and stable RNA interference agents. The present invention provides improved yields and avoids the use of lead tetraacetate for decarboxylative acetylation which decreases the overall cost of production by removing the need for lead remediation and offers a significant reduction in the environmental costs in production.

    专利号:US-4104140-A
    优先权日:1972-10-05
    标题:Process for the electrochemical synthesis of organic metal compounds
    发明人:EISENBACH WILHELM; LEHMKUHL HERBERT; WILKE GUNTHER
    权利人:STUDIENGESELLSCHAFT KOHLE MBH
    摘要:Process for reacting an H-acidic organic compound, in which the acidic H-atom is bonded to the organic radical by an oxygen or a sulphur atom, e.g. an alcohol, with a metal having a standard potential which is more positive than -1.66 volts and which at most incompletely reacts with the H-acidic compound under current-free conditions, e.g. Ni, Co, Fe, Mn, Sb, Cu, or Au. The H-acidic compound or a solution thereof is a polar solvent is made conducting by addition of a soluble salt of chlorine, bromine or iodine, and is electrolyzed at a temperature of up to 150° C, using said metal as the anode, for production of the alcoholate.

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    合成参考文献

    合成方法参考DOI号:10.1016/j.molstruc.2017.06.023
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