CAS: 791616-55-2; (11Br)-4-Hydroxy-2,6-Bis(Triphenylsilyl)Dinaphtho[2,1-D:1',2'-F][1,3,2]Dioxaphosphepine 4-Oxide
- 英文名称(11Br)-4-Hydroxy-2,6-Bis(Triphenylsilyl)Dinaphtho[2,1-D:1',2'-F][1,3,2]Dioxaphosphepine 4-Oxide
- 中文名称(R)-(-)-3,3'-双(三苯甲硅烷基)-1,1'-联萘-2,2'-二酚膦酸酯
- IUPAC名称(11bR)-4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- 其它别名(R)-3,3 Inverted Exclamation Mark -Bis(Triphenylsilyl)-1,1 Inverted Exclamation Mark -Binaphthyl-2,2 Inverted Exclamation Mark -Diyl Hydrogenphosphate ; R-3,3'-Bis(Triphenylsilyl)-1,1'-Binaphthyl-2,2'-Diyl Hydrogenphosphate ; S-3,3'-Bis(Triphenylsilyl)-1,
- CAS编号791616-55-2
- MFCD编号:MFCD09265079
- EINECS号:635-984-6
- 分子式:C56H41O4PSi2分子量:865.07
- 产品CID: 1785866
- 产品分类化学试剂 → 有机试剂 → 膦配体
- 相似结构搜索
- InChIKey: BDQOCXQVIFQJRK-UHFFFAOYSA-N
- BDQ°CXQVIFQJRK-UHFFFAOYSA-N
- 计算化学: 氢键受体数4.0氢键供体数1.0可旋转键数8.0
物理性质
MSDS等安全信息
欧盟法规
C&L通报合成工艺路线路线简述
- 111822-69-6 = 791616-55-2
反应条件:1.1 Reagents: Triethylamine,Phosphorus Oxychloride Solvents: Dichloromethane; 12 H,Reflux1.2 Reagents: Pyridine,Hydrochloric Acid Solvents: Water; 12 H,Reflux
标题:Desymmetrizing Enantio- And Diastereoselective Selenoetherification Through Supramolecular Catalysis
作者:See,Jie Yang; Yang,Hui; Zhao,Yu; Wong,Ming Wah; Ke,Zhihai; Et Al
参考文献:Acs Catalysis 日期:2018 卷标:8(2) 页码:850-858]
111822-69-6 = 791616-55-2 [标题:Reaction Conditions
标题:Oxidative Asymmetric Aza-Friedel-Crafts Alkylation Of Indoles With 3-Indolinone-2-Carboxylates Catalyzed By A Binol Phosphoric Acid And Promoted By Ddq
作者:Yarlagadda,Suresh; Sridhar,B.; Subba Reddy,Basireddy Venkata
参考文献:Chemistry - An Asian Journal 日期:2018 卷标:13(10) 页码:1327-1334]
111822-69-6 = 791616-55-2
反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Pyridine; Rt; 5 H,70 °C1.2 Reagents: Water; 2 H,70 °C
标题:Synthesis Of Novel Chiral Phosphoric Acid-Bearing Two Acidic Phenolic Hydroxyl Groups And Its Catalytic Evaluation For Enantioselective Friedel-Crafts Alkylation Of Indoles And Enones
作者:Liu,Xiong-Li; Yu,Zhang-Biao; Pan,Bo-Wen; Chen,Lin; Feng,Ting-Ting; Et Al
参考文献:Journal Of Heterocyclic Chemistry 日期:2015 卷标:52(2) 页码:628-634]
107473-14-3 + 1352734-11-2 = 791616-55-2 + 1352151-17-7
反应条件:1.1 Solvents: Dichloromethane; 33 H,23 °C
标题:Phosphate Ligands In The Gold(I)-Catalyzed Activation Of Enynes
作者:Raducan,Mihai; Moreno,Maria; Bour,Christophe; Echavarren,Antonio M.
参考文献:Chemical Communications (Cambridge 日期:2012 卷标:48(1) 页码:52-54]
111822-69-6 = 791616-55-2
反应条件:1.1 Reagents: Butyllithium,Phosphorus Oxychloride Solvents: Tetrahydrofuran; -20 °C -> 0 °C1.2 Reagents: Triethylamine Solvents: Water; 18 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water; 6 H,Reflux
标题:Bronsted Acid-Catalyzed,Highly Enantioselective Addition Of Enamides To In Situ-Generated Ortho-Quinone Methides: A Domino Approach To Complex Acetamidotetrahydroxanthenes
作者:Saha,Satyajit; Schneider,Christoph
参考文献:Chemistry - A European Journal 日期:2015 卷标:21(6) 页码:2348-2352]
111822-69-6 = 791616-55-2
反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Pyridine; Rt; 24 H,95 °C1.2 Reagents: Water; 0 °C; 6 H,95 °C
标题:Enantioselective Organocatalytic Reductive Amination
作者:Storer,R. Ian; Carrera,Diane E.; Ni,Yike; Macmillan,David W. C.
参考文献:Journal Of The American Chemical Society 日期:2006 卷标:128(1) 页码:84-86]
111822-69-6 = 791616-55-2
反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Pyridine; Rt; 24 H,95 °C1.2 Solvents: Water; 8 H,95 °C1.3 Reagents: Hydrochloric Acid Solvents: Dichloromethane,Water
标题:Asymmetric Synthesis Of 3-Amino-δ-Lactams And Benzo[a]Quinolizidines By Catalytic Cyclization Reactions Involving Azlactones
作者:Jiang,Jun; Qing,Jian; Gong,Liu-Zhu
参考文献:Chemistry - A European Journal 日期:2009 卷标:15(29) 页码:7031-7034]
111822-69-6 = 791616-55-2
反应条件:1.1 Reagents: Phosphorus Oxychloride Solvents: Pyridine; Rt; 5 H,50 °C1.2 Solvents: Water; 1 H,70 °C
标题:Enantioselective Direct Aza Hetero-Diels-Alder Reaction Catalyzed By Chiral Bronsted Acids
作者:Liu,Hua; Cun,Lin-Feng; Mi,Ai-Qiao; Jiang,Yao-Zhong; Gong,Liu-Zhu
参考文献:Organic Letters 日期:2006 卷标:8(26) 页码:6023-6026
专利信息
专利号:WO-2017083719-A1
优先权日:2015-11-13
标 题:Transition metal free methods of synthesis of biaryl compounds
发明人：GAO HONGYIN; KURTI LASZLO
权利人:UNIV RICE WILLIAM M
摘要:The present disclosure provides methods of preparing biaryl compounds which do not require transition metal catalysts. In yet another aspect, the present disclosure provides pharmaceutical compositions comprising compounds as described herein and pharmaceutically acceptable carriers.
专利号:US-7517828-B2
优先权日:2003-04-25
标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst
发明人：AKIYAMA TAKAHIKO
权利人:TOAGOSEI CO LTD
摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.
专利号:US-2006276329-A1
优先权日:2003-04-25
标题:Asymmetric synthesis catalyst based on chiral brsnsted acid and method of asymmetric synthesis with the catalyst
专利号:EP-1623971-A1
优先权日:2003-04-25
标 题:Asymmetric-synthesis catalyst based on chiral broensted acid and method of asymmetric synthesis with the catalyst
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 19.
摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 23.
摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 25.
摘要:Schneider, C.; Sickert, M., Science of Synthesis Knowledge Updates, (2017) 3, 432.
摘要:Chen, Y.-C.; Cui, H.-L., Science of Synthesis: Asymmetric Organocatalysis, (2012) 2, 833.
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