= 79-00-5 反应条件:1.1 Reagents: Hydrochloric Acid 标题:Shaped Catalyst Containing Cupric Chloride And/or Copper Oxychloride,Its Preparation,And Its Use For The Oxychlorination Of Ethylene To 1,2-Dichloroethane 参考文献:Federal Republic Of Germany]
= 79-00-5 + 33455-24-2 [标题:Reaction Conditions 标题:Reaction Of Phosphorus Pentachloride With Some Halo Olefins 作者:Zinov'Ev,Yu. M.; Kulakova,V. N.; Soborovskii,L. Z. 参考文献:Zhurnal Obshchei Khimii 日期:1957 卷标:27 页码:151-6]
= 79-00-5 反应条件:1.1 Reagents: Chlorine 标题:Chlorine 作者:Cornel,Veronica 参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-4]
= 79-00-5 [标题:Reaction Conditions 标题:Progress Analysis Of Direct Chlorination Of Ethylene To Dichloroethane 作者:Mu,Xiaolei; Qi,Lanzhi; Jia,Chunge; Li,Douxing 参考文献:Shiyou Huagong 日期:2015 卷标:44(6) 页码:701-704]
156-60-5 = 79-00-5 反应条件:1.1 Reagents: Chlorine Catalysts: Dimethylformamide; 38 - 39 °C 标题:Improvement Of A Process For Purification Of Chlorine Derivatives Of Methane. Purification By Chlorination 作者:Uskach,Ya. L.; Zotov,S. B.; Popov,Yu. V.; Zanaveskin,L. N.; Varshaver,E. V. 参考文献:Entsiklopediya Inzhenera-Khimika 日期:2012 卷标:(2) 页码:35-38
专利号:US-11926589-B2 优先权日:2019-07-09 标 题 :Process for the synthesis of non-racemic cyclohexenes 发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND 权利人:BASF CORP; CALIFORNIA INST OF TECHN 摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.
专利号:US-2022298204-A1 优先权日:2019-07-05 标题 :Synthesis of a-amanitin and its derivatives 发明人:SIEGERT MARY-ANN; KNITTEL CAROLINE HERTA; SÜSSMUTH RODERICH 权利人:PURE BIOORGANICS SIA 摘要:The present invention relates to the chemical synthesis of α-amanitin and its derivatives. The present invention also relates to intermediate products of the α-amanitin synthesis.
专利号:US-4288608-A 优先权日:1978-06-01 标题:Synthesis of anthracyclines 发明人:JOHNSON FRANCIS; KIM KYOUNG S 权利人:RESEARCH CORP 摘要:There is provided a novel method of synthesizing certain heterocyclic quinones. In particular there is provided a novel and regiospecific synthesis of 9-acetyl-6,11-dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-quinone (7,9-dideoxydaunomycinone) which is known intermediate in the synthesis of daunomycinone. There is also provided a method of preparing analogs of 7,9-dideoxydaunomycinone which thus provide for the preparation of known and desired analogs of daunomycinone. Daunomycinone is a known compound which is an intermediate in the preparation of the clinically accepted naturally-occurring antitumor antibiotics daunomycin and its derivitive adriamycin.
专利号:US-5512701-A 优先权日:1995-06-07 标题:Process for the synthesis of vinyl sulfenic acid derivatives 发明人:HOARD DAVID W; LUKE WAYNE D 权利人:LILLY CO ELI 摘要:The present invention is directed to a new process for the synthesis of vinyl sulfenic acid derivatives. These compounds are useful for the synthesis of benzo[b]thiophenes, in particular 2-aryl-benzo[b]thiophenes.
专利号:US-4870199-A 优先权日:1986-04-30 标题 :Processes for the synthesis of diprotected R[R*,S*]-3,5-dihydroxy-6-oxohexanoate esters 发明人:CHEN KAU-MING; HARDTMANN GOETZ E; KAPA PRASAD K; LEE GEORGE T; LINDER JEROME; WATTANASIN SOMPONG 权利人:SANDOZ PHARMACEUTICALS CORP 摘要:Process for the synthesis of compounds of the formula in R[R*,S*] enantiomeric form, wherein each P1 is independently an hydroxy group-protecting group, and R2z is C1-4alkyl, benzyl or allyl, comprising, as a key step when R2z is R2x, the reaction of the compound of the formula in (S) enantiomeric form with a compound of the formula Mg &cir& +2 ((-)OOC-CH2-COOR2x)2 to obtain a compound of the formula in (S) enantiomeric form, and, as a key step when R2z is R2y, the reaction of a compound of the formula in (S) enantioimeric form with a compound of the formula Li(+)(-)CH2-COOR2y to obtain a compound of the formula in (S) enantiomeric form, wherein R2x is primary or secondary C1-4alkyl, benzyl or allyl, R2y is C1-4alkyl not containing an asymmetric carbon atom, and R3' is methyl or ethyl, processes for the synthesis of compounds of the formula comprising reacting a compound of the formula with the reaction product of a strong base and a compound of the formula optionally followed by, when R2z is allyl, cleavage of the allyl and P1 groups to obtain the corresponding compound of the formula wherein each R7 is methyl or ethyl, R is as defined in the specification, and each P1 independently and R2z are as defined above, and the compounds of the formula wherein R and each R7 are as defined above.
专利号:US-2023339844-A1 优先权日:2020-09-17 标题:A process for the synthesis of anthranilic acid/amide compounds and intermediates thereof 发明人:MAHAPATRA TRIDIB; PATRA PRANAB KUMAR; KLAUSENER ALEXANDER G M; MAL SANJIB; SHARMA RAJU 权利人:PI INDUSTRIES LTD; PI INDUSTRIES LTD 摘要:The present invention disclosed a process for the synthesis of compound of formula (Z) or a salt thereof, n n n n n n n n n n wherein, R, R 1 , R 2 , R 3 and R 10 are as defined in the detailed description. The process further comprises the synthesis of an anthranilic diamide compound of formula (I).
参考标题:Cyclofunctionalisation Of Epoxyalcohol Derivatives. 1. Delivery Of Functionalised Carbon For Stereospecific Synthesis Of Dihydrofurans And Dihydroxyacids 作者:Stuart W. Mccombie,Bandarpalle B. Shankar,Ashit K. Ganguly 摘要:E-2-(Phenylsulfonyl)Vinyl Ethers Of 2,3-Epoxyalcohols Are Stereospecifically Rearranged To 3-(Phenylsulfony])-4-(1-Hydroxyalkyl)-4,5-Dihydrofurans On Treatment With Lda. Oxidation Of These Compounds Or The Derived Des-Sulfonyl Compounds Provides Esters Or Lactones Which Correspond To Regiospecific Delivery Of -Co2H Or -Ch2Co2H To C-2, With Inversion.
合成参考文献
摘要:Archiv fuer Hygiene und Bakteriologie., 116(131), 1936 摘要:Toxicology and Applied Pharmacology., 10(119), 1967 [] 摘要:Quarterly Journal of Pharmacy & Pharmacology., 7(205), 1934 摘要:Toxicology and Applied Pharmacology., 9(139), 1966 [] 摘要:Union Carbide Data Sheet., 6/28/1972