CAS: 2800-96-6; Tin(Iv) Acetate

该化合物是有机锡化合物,其特点是其四乙酸结构,锡与四个乙酸集团相协调,该化合物一般视其形态和纯度而呈现无色的黄色液体或固体色状,其作用是有机合成中的试剂,特别是在涉及形成碳-碳联结的反应和各种聚合过程中的催化剂方面,锡四亚乙酸盐具有中度毒性,在使用期间需要小心处理和采取适当的安全措施.该化合物在有机溶剂中可溶解,这增强了其在各种化学应用中的用途.此外,锡四亚乙酸酯在水分存在时可以进行水解,从而形成乙酸和氧化锡,这是储存和应用中的一个重要考虑因素.

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acetic acid tin acetic anhydride acetate3-(4-chloro-5-cyclopentyloxy-2-fluorophenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione tin tetraethyltin 1,4-diacetoxynaphthalene

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    专利号:US-2022081788-A1
    优先权日:2019-12-27
    标题:General method for the synthesis of FeCoNiCu-based high-entropy alloy and their application for electrocatalytic water splitting
    发明人:ZHU HAN; ZHANG SONGGE; CAI JIAN; LI HUILIN; DU MINGLIANG
    权利人:UNIV JIANGNAN
    摘要:The disclosure herein discloses a general method for the synthesis of FeCoNiCu-based high-entropy alloy and their application for electrocatalytic water splitting, belonging to the technical field of preparation of composite materials. The catalytic material for electrolysis of water includes a reaction active material and a support. The reaction active material is FeCoNiCu-based high-entropy alloy nanoparticles such as FeCoNiCuSn, FeCoNiCuMn, FeCoNiCuV or the like. The support is a carbon nanofiber material prepared by electrospinning. The catalytic material for electrolysis of water prepared in the disclosure herein has a high specific surface area, which facilitates diffusion of the electrolyte and desorption of gas. By using the catalytic material for electrolysis of water, hydrogen and oxygen can be produced under alkaline conditions, and the hydrogen production rate under high voltage is much higher than that of a 20% Pt/C electrode. Meanwhile, the carbon nanofibers can effectively protect the high-entropy alloy nanoparticles from erosion of the electrolyte, and endow the catalytic material with good stability.

    专利号:US-10294336-B2
    优先权日:2014-11-27
    标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use
    发明人:KOENIG CHRISTIAN; EMGE ANDREAS; OTERO MARTINEZ IRAN
    权利人:BASF SE
    摘要:The present invention relates to the synthesis of polymer polyols in unsaturated polyols as liquid phase, polymer polyols and their use.

    专利号:US-2017246619-A1
    优先权日:2014-09-26
    标 题 :Solid state synthesis of oxidative dehydrogenation catalysts
    发明人:BASSET JEAN-MARIE; ZHU HAIBO; ROSENFELD DEVON C; LAVEILLE PACO
    权利人:DOW GLOBAL TECHNOLOGIES LLC
    摘要:Synthesize a nickel oxide-based oxidative dehydrogenation catalyst via a solvent-free process that comprises sequential steps a. mixing without added solvent a combination of a solid nickel precursor, a solid oxalate or oxalic acid and, optionally, a doping amount of a metal precursor for a period of time sufficient to convert the combination to a visually homogenous mixture; and b. calcining the visually homogeneous mixture at a temperature within a range of from greater than 250° C. to less than 800° C. for a time within a range of from 30 minutes to 360 minutes in an oxygen-containing atmosphere, preferably air, to form a calcined oxidative dehydrogenation catalyst. As a modification of the process, add an intermediate step between steps a. and b. to dry the homo geneous mixture at a temperature within a range of from 50° C. to 90° C. for a period of time within a range of from 10 minutes to 600 minutes to form a dried mixture. The resulting catalyst may be used in oxidative dehydrogenation of ethane.

    专利号:US-9126848-B2
    优先权日:2009-12-29
    标题:Synthesis of nanoparticles by means of ionic liquids
    发明人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL
    权利人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL; LEIBNIZ INSITUT FUER NEUE MATERIALIEN GEMEINNUETZIGE GMBH
    摘要:A method for producing nanoscale particles by means of ionic liquids produces highly crystalline particles. The ionic liquids can be easily regenerated.

    专利号:US-9517945-B2
    优先权日:2012-11-28
    标 题:Low-temperature route for precision synthesis of metal oxide nanoparticles
    发明人:ITO DAISUKE; HUTCHISON JAMES E
    权利人:UNIV OREGON
    摘要:Methods for making metal oxide nanoparticles, including mixed metal oxides and core-shell metal oxide nanoparticles, are disclosed. A solution comprising a metal carboxylate and a carboxylic acid is combined with a solvent comprising an alcohol heated to a temperature ≦250° C. for an effective period of time to form metal oxide nanoparticles. The metal may be a group IIIA metal, a group IVA metal, a transition metal, or a combination thereof. A metal oxide shell may be deposited onto metal oxide nanoparticles by dispersing the metal oxide nanoparticles in an alcohol, adding a metal carboxylate, and maintaining the reaction at a temperature ≦200° C. for an effective period of time to form core-shell nanoparticles. The nanoparticles may have a relative size dispersity of ≦20%, and may further comprise a plurality of carboxylic acid, carboxylate, and/or alcohol ligands coordinated to the nanoparticles' outer surfaces.

    专利号:US-4705866-A
    优先权日:1985-12-26
    标 题 :Synthesis of N-halogenated phenyl maleimide compounds with tin containing catalysts
    发明人:GASTINGER ROBERT G
    权利人:ATLANTIC RICHFIELD CO
    摘要:A process for the preparation of N-brominated or N-chlorinated phenylmaleimide by reacting maleic anhydride and a brominated or chlorinated aniline compound at temperatures of from about 100 DEG C. to about 210 DEG C. in the presence of tin containing catalyst compound and optionally an inert solvent.

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    主要参考文献

    [参考文献]: Ji-Won Jung, Et Al. Glassy Metal Alloy Nanofiber Anodes Employing Graphene Wrapping Layer: Toward Ultralong-Cycle-Life Lithium-Ion Batteries. Acs Nano. 2015 Jul 28;9(7):6717-27.

    合成参考文献


    参考文献:10.1007/s10924-025-03565-w
    摘要:Kricheldorf HR, Weidner SM. H2O-Initiated Polymerization of L-Lactide. J Polym Environ. 2025 Apr 05;33(6):2843–57. doi: 10.1007/s10924-025-03565-w.
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