CAS: 25312-34-9; (E)-4-(2,6,6-Trimethylcyclohex-2-En-1-yl)But-3-En-2-Ol
该化合物是属于单细胞醇一类的化学化合物; 色色的黄色液体,具有典型的花粉芳香,经常与紫色和玫瑰气味有关,在香味工业中具有价值. -异诺醇因其抗氧化特性而著称,并用于各种用途,包括化妆品,香水和食品调味. 该化合物具有相对较低的挥发性,有助于其制剂的稳定性. 它的分子结构具有环状环状,许多梯子都有其特征,并且可存在于不同的立体异构体形态中. -异诺醇在有机溶剂中溶解,但在水中溶解作用有限. 安全数据表明,应谨慎处理该物质,因为它可能会在敏感个人中引起皮肤刺激或过敏反应.
- 英文名称(E)-4-(2,6,6-Trimethylcyclohex-2-En-1-yl)But-3-En-2-Ol
- 中文名称α-紫罗兰醇
- IUPAC名称(E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-ol
- 其它别名4-(2,6,6-三甲基-2-环己烯-1-基)-3-丁烯-2-醇; Alpha-Ionol
- CAS编号25312-34-9
- MFCD编号:MFCD00036594
- EINECS号:246-815-7
- FDA UNII编号:4QI2W5Y52K
- 分子式:C13H22O分子量:194.32
- 产品CID: 1212540
- 产品分类有机原料→分子砌块→脂肪环类化合物→环己烷类化合物
相似化合物
127-51-5 5208-93-5 127-41-3物理性质
- 沸点127 °C at 15 mmHg
- 闪点96.2 °C
- 密度0.941g/cm3
- pKa:14.40±0.20(预测)
- PSA:20.23
- LogP:3.3059
- 折射率1.524
- 蒸汽压0.0013mmHg at 25°C
- 溶解性Chloroform (Sparingly), Methanol (Slightly)
- 敏感性1. 存在于烟叶中。
- 外观形态无色油状物
- 储存条件冰箱, 置于惰性气氛下
- 产品应用α-紫罗兰醇(25312-34-9)的用途:GB 2760―1996规定为允许使用的食品用香料.
- 性质描述沸点 127°C15mm Hg ,密度 0.918g/mLat 20°C ,折光率 n 20/D 1.491
MSDS等安全信息
上下游产品
CAS号127-41-3 紫罗兰酮 | CAS号24190-29-2 [R-(E)]-4-(2,6,... | CAS号555-31-7 异丙醇铝 | CAS号67-63-0 异丙醇 | CAS号127-41-3 紫罗兰酮 | CAS号783324-41-4 acetic acid,4-(... | CAS号79-76-5 4-(2,2-二甲基-6-亚甲... | CAS号475-03-6 1,2,3,4-四氢-1,1,... | CAS号84651-10-5 1-butyl-2,4,6-t... | CAS号85329-77-7 1,1,4,4-tetrame... | CAS号84651-11-6 1-butyl-2,3,6-t... | CAS号85329-78-8 1,1,4,4-tetrame...合成工艺路线路线简述
📜Alpha-Ionone置于sodium Tetrahydroborate,Erbium(III) Triflate体系中,用 2-甲基四氢呋喃 用作溶剂,化学反应 0.08H,以99%的收率获得alpha-紫罗兰醇
参考文献:Eco-Friendly Stereoselective Reduction Of α,β-Unsaturated Carbonyl Compounds By Er(Otf)3/nabh4 In 2-Methf
标题:Eco-Friendly Stereoselective Reduction Of α,β-Unsaturated Carbonyl Compounds By Er(Otf)3/nabh4 In 2-Methf
摘要:An Operationally Simple And Environmentally Benign Catalytic Procedure Has Been Developed To Selectively Reduce Different Alpha,Beta-Unsaturated Ketones. The Corresponding Allylic Alcohols Are Obtained With High Chemo-And Diastereoselectivity Using Er(Otf)(3) And Nabh4 In 2-Methf. This Protocol Reduces The Amount Of Catalyst And Nabh4 Needed,Compared To Classical Procedures And The Stages Of Extraction/purification Are Carried Out In Aqueous Solutions Avoiding The Use Of Toxic Solvents. Taking Into Account That Er(Otf)(3) Can Be Considered Even Less Toxic Than Table Salt And The 'Greenness' Of 2-Methf As A Solvent,The System Er(Otf)(3)/2-Methf Can Be Proposed As A Cheap,Efficient,And Environmentally Sustainable Reduction System For The Synthesis Of Allylic Alcohols. (C) 2014 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tet.2014.12.005
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:CN-102617659-A
优先权日:2012-03-09
标题:Synthesis of α-ionol glucoside and its flavoring application in cigarettes
专利号:CN-100361948-C
优先权日:2005-12-30
标题:Synthesis of ketone-substituted alpha-ionone, ketone-substituted beta-ionone, ether and ester derivative by one-step method
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Food and Chemical Toxicology., 26(359), 1988
📝 需求与反馈
尽可能描述清楚需求与问题信息
