CAS: 193-39-5; Indeno[1,2,3-Cd]Pyrene

该化合物是多环芳烃[1,2,3-cd],其特点是由五个相互连接的芳香环环组成,由5个相互连接的芳香环组成,在室内温度下是固体,一般是黑晶物质,以其高度稳定性和耐降解性而闻名,使其在环境中具有持久性; 丙烯主要在化石燃料中找到,在煤和油等有机材料的不完全燃烧期间生产; 承认其潜在的致癌性,因为它可形成DNA吸附剂,导致诱变性效应; 该物质在水中溶性不强,但在有机溶剂中可溶解,影响其在环境环境中的行为; 由于其毒理学特征,该物质受到监管审查,特别是其在空气,土壤和水中的存在.

结构式图片

相似化合物

205-99-2 188-94-3 203-33-8

物理性质

MSDS等安全信息

欧盟法规

ECHA物质ECHA物质C&L通报欧盟《水框架指令》附件XREACH预注册

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CAS号377737-93-4 1-(2-bromopheny... | CAS号1714-29-0 1-溴芘 | CAS号244205-40-1 2-溴苯硼酸 | CAS号824-91-9 1-(甲氧基甲氧基)苯 | CAS号108-95-2 苯酚 | CAS号1732-26-9 4-溴芘 | CAS号111189-50-5 2-pyren-1-ylcyc... | CAS号115-10-6 二甲醚 | CAS号111209-32-6 2-pyren-4-ylcyc... | CAS号102420-56-4 IP-1,2-Diol | CAS号99520-63-5 1,2-dihydroinde...

合成工艺路线路线简述

    📜1-溴芘置于重铬酸吡啶,正丁基锂,Ppa,2,3-二氯-5,6-二氰基-1,4-苯醌体系中,用 乙醚,N,N-二甲基甲酰胺 用作溶剂,化学反应 16.5H,反应生成茚并(1,2,3-Cd)芘
    参考文献:多环芳族荧光素的合成
    标题:多环芳族荧光素的合成
    摘要:描述了一种通用的合成方法,用于合成含有荧蒽环系统的多环芳烃.该方法需要通过芳基锂衍生物与环己烯氧化物的反应将茚环稠合到交替的烃上.
    Doi:10.1016/s0040-4039(01)81008-X

    海关参考信息

    专利信息


    专利号:US-9758499-B2
    优先权日:2014-06-12
    标 题:Stereo controlled synthesis of (E,Z)-dienals via tandem Rh(I) catalyzed propargyl claisen rearrangement
    发明人：VIDHANI DINESH V; KRAFFT MARIE E; ALABUGIN IGOR
    权利人:UNIV FLORIDA STATE RES FOUND
    摘要:A novel Rh(I)-catalyzed approach to synthesizing functionalized (E,Z) dienal compounds has been developed via tandem transformation where a stereoselective hydrogen transfer follows a propargyl Claisen rearrangement. Z-Stereochemistry of the first double bond suggests the involvement of a six-membered cyclic intermediate whereas the E-stereochemistry of the second double bond stems from the subsequent protodemetallation step giving an (E,Z)-dienal. The reaction may be represented by the following sequence.

    专利号:US-9023308-B2
    优先权日:2011-03-15
    标题:Facile synthesis of graphene, graphene derivatives and abrasive nanoparticles and their various uses, including as tribologically-beneficial lubricant additives

    专利号:CA-2857947-A1
    优先权日:2011-03-15
    标题 :Facile synthesis of graphene, graphene derivatives and abrasive nanoparticles and their various uses, including as tribologically-beneficial lubricant additives

    专利号:US-9573871-B2
    优先权日:2014-06-12
    标题 :Stereo controlled synthesis of (E,Z)-dienals via tandem Rh(I) catalyzed propargyl claisen rearrangement

    专利号:US-9700872-B1
    优先权日:2016-07-01
    标题:Superpolar chromatographic stationary phases and extraction sorbents and their methods of synthesis
    发明人：KABIR ABUZAR; FURTON KENNETH G
    权利人:KABIR ABUZAR; FURTON KENNETH G; UNIV FLORIDA INT
    摘要:A superpolar sorbent network is a sol-gel network of at least one metal oxide precursor condensed and at least one polyhydroxy molecule. The metal oxide precursor is a silicate precursor, aluminate precursor, titanate precursor, zirconate precursor, germinate precursor, or any combinations thereof, and the polyhydroxy molecule has a multiplicity of hydroxyl groups. The polyhydroxy molecule can be an organic molecule derived from nature. The superpolar sorbent network can be used as a particulate or bulk sorbent for sampling or removal of analytes or contaminants from an environment or can be coated on a tube or particulate substrate for use as a chromatographic stationary phase.

    专利号:WO-2012125854-A1
    优先权日:2011-03-15
    标题 :Facile synthesis of graphene, graphene derivatives and abrasive nanoparticles and their various uses, including as tribologically-beneficial lubricant additives

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    主要参考文献

    参考标题:Synthesis Of Cyclopenta-Fused Polycyclic Aromatic Hydrocarbons Utilizing Aryl-Substituted Anilines
    作者:Yeojin Choi,Tanmay Chatterjee,Jun Kim,Jun Soo Kim,Eun Jin Cho
    摘要:Cyclopenta-Fused Polycyclic Aromatic Hydrocarbons (Cp-Pahs), Potentially Electronically And Biologically Highly Active Materials, Were Synthesized From Readily Available 2-Aryl-Substituted Anilines. Reactions Occur Under Extremely Mild, Room Temperature Conditions Using Tbuono As The Sole Reagent. The Use Of A Nitrite Source Generates A Reactive Diazonium Intermediate In Situ That Then Reacts With

    合成参考文献


    参考文献:10.1021/es201443z
    摘要:Wang W, Jariyasopit N, Schrlau J, Jia Y, Tao S, Yu T, Dashwood RH, Zhang W, Wang X, Simonich SLM. Concentration and Photochemistry of PAHs, NPAHs, and OPAHs and Toxicity of PM2.5 during the Beijing Olympic Games. Environ. Sci. Technol. 2011 Jul 18;45(16):6887–95. doi: 10.1021/es201443z.
    参考文献:10.1007/s10646-011-0737-7
    摘要:Serafim A, Lopes B, Company R, Cravo A, Gomes T, Sousa V, Bebianno MJ. A multi-biomarker approach in cross-transplanted mussels Mytilus galloprovincialis. Ecotoxicology. 2011 Nov;20(8):1959–74. doi: 10.1007/s10646-011-0737-7.
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