CAS: 151417-38-8; 4,4''-Diiodo-5'-(4-Iodophenyl)-1,1':3',1''-Terphenyl

该化合物其结构特征为该化合物其结构特征为中苯环,以三组四联苯组替代,该化合物具有高度的卤化特性,增强了其电子特性和材料科学的潜在应用,特别是在有机电子和光质学中,这增加了其电子特性和潜在应用;碘原子的存在促使其分子重量增加,并可能影响其溶解性和再活性;此外,该化合物可能呈现出有趣的光学特性,因为由苯组构成的同系系统,使它成为用于发光源装置或作为有机合成构件的一个候选体;其合成通常涉及多步反应,而且由于含碘化合物的毒性,处理需要谨慎小心.

结构式图片

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855239-61-1 612-71-5 7511-49-1

物理性质

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上下游产品

CAS号13329-40-3 4'-碘代苯乙酮 | CAS号612-71-5 1,3,5-三苯基苯 | CAS号10450-60-9 高碘酸 | CAS号71866-86-9 1,3,5-三(4-乙炔苯基)苯 | CAS号6326-64-3 1,3,5-三(4-联苯基)苯

合成工艺路线路线简述

    📜4-碘代苯乙酮置于nano-Silica Sulfuric Acid体系中,用 Neat (No Solvent) 用作溶剂,化学反应 0.42H,以83%的收率获得1,3,5-三(4-碘苯基)苯
    参考文献:Nano-Silica Sulfuric Acid Catalyzed The Efficient Synthesis Of 1,3,5-Triarylbenzenes Under Microwave Irradiation
    标题:Nano-Silica Sulfuric Acid Catalyzed The Efficient Synthesis Of 1,3,5-Triarylbenzenes Under Microwave Irradiation
    摘要:纳米二氧化硅硫酸作为异相,环保且可重复使用的催化剂,被用于通过乙酰苯的三重自缩合反应合成1,3,5-三芳基苯.所有反应均在无溶剂条件和微波辐射下进行.短反应时间,高产率,产品易于分离和纯化以及该催化剂的非常好重复性是制备1,3,5-三芳基苯选择这种催化剂的主要原因.
    Doi:10.1007/s13738-012-0089-0

    专利信息


    专利号:US-8329769-B2
    优先权日:2009-12-10
    标题:Facile synthesis of microporous triple-bond based polymer networks using acetylene gas as a building unit
    发明人：KANG JEUNG-KU; CHOI JUNG-HOON; CHOI KYUNG-MIN; JEON HYUNG-JOON; CHOI YOON-JEONG; LEE YEOB
    权利人:KANG JEUNG-KU; CHOI JUNG-HOON; CHOI KYUNG-MIN; JEON HYUNG-JOON; CHOI YOON-JEONG; LEE YEOB; KOREA ADVANCED INST SCI & TECH
    摘要:Disclosed is a method for synthesis of micro-porous triple-bond based polymer networks using acetylene gas. According to the disclosed methods for synthesis of micro-porous triple-bond based polymer networks, acetylene gas interconnects building units having iodine and/or bromine functional groups by coupling reactions to provide micro-porous triple-bond based polymer networks.

    专利号:US-2011152393-A1
    优先权日:2009-12-10
    标题 :Facile Synthesis of Microporous Triple-Bond Based Polymer Networks Using Acetylene Gas as a Building Unit

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    主要参考文献

    参考标题:Ptsa-Catalyzed Green Synthesis Of 1,3,5-Triarylbenzene Under Solvent-Free Conditions
    作者:Yanan Zhao,Jian Li,Chunju Li,Kun Yin,Dongyan Ye,Xueshun Jia
    摘要:An Economical And Green Conversion Of Acetophenones Into 1,3,5-Triarylbenzenes Catalyzed By Ptsa Is Described. The Present Method Is Facile And Chemo-Selective Without Using Any Metal Catalyst Or Solvent.

    合成参考文献


    参考文献:10.1007/978-981-16-0463-8_29
    摘要:Huang H, Ji W, Wang W. Organic Transformations Enabled by Yolk–Shell and Core–Shell Structured Catalysts. 2021. In: Nanostructure Science and Technology.
    参考文献:10.1007/s11243-022-00519-2
    摘要:Kim D, Jadhav JR, Park J, Jung O. C3-symmetric tripalladium(II) complex for catalysis via geometrical coincident interaction with C3-symmetric substrate. Transit Met Chem. 2022 Dec 17;48(1):3–9. doi: 10.1007/s11243-022-00519-2.
    参考文献:10.1007/s00214-023-02987-w
    摘要:James A, Swathi RS. Halogen bonding: a designer strategy for graphyne-like two-dimensional architectures. Theor Chem Acc. 2023 Apr 20;142(5). doi: 10.1007/s00214-023-02987-w.
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