CAS: 1270-98-0; Cyclopentadienyltitanium Trichloride

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CAS号1271-19-8 二氯二茂钛 | CAS号7550-45-0 四氯化钛 | CAS号74304-33-9 | CAS号3559-74-8 三甲基甲硅烷基环戊二烯(异构体混合物) | CAS号7791-25-5 磺酰氯 | CAS号87654-36-2 [(η5-C5H5)TiCl]... | CAS号7790-89-8 一氟化氯 | CAS号12149-47-2 CpTi(OPh)3 | CAS号1271-19-8 二氯二茂钛 | CAS号59307-41-4 cyclopenta-2,4-... | CAS号79269-70-8 cyclopenta-1,3-... | CAS号87738-99-6 | CAS号1282-43-5 cyclopenta-1,3-... | CAS号51203-49-7 (η7-环庚三烯)(η5-环戊... | CAS号75-77-4 三甲基氯硅烷 | CAS号35398-24-4 dichloro(η5-cyc... | CAS号7727-37-9 氮气

📜二氯二茂钛置于盐酸,氮,Magnesium体系中,用 四氢呋喃 用作溶剂,以12%的收率获得三氯一茂钛
参考文献:The Application Of 13C And 1H NMR Spectroscopy To The Investigation Of The Dinitrogen Fixation Process In The System (η-C5H5)2Ticl2-Mg
标题:The Application Of 13C And 1H NMR Spectroscopy To The Investigation Of The Dinitrogen Fixation Process In The System (η-C5H5)2Ticl2-Mg
摘要:
Doi:10.1016/0022-328X(83)80218-6

专利信息

专利号:US-11884606-B2
优先权日:2021-11-29
标 题:Monoalkyl cyclopentadiene compounds and processes for preparing same
发明人：BALASANTHIRAN VAGULEJAN; LANEMAN SCOTT A; ALKEMA JON; KERMIS THOMAS
权利人:ENTEGRIS INC
摘要:The disclosure provides methodology for the synthesis of mono-alkylated cyclopentadiene structures, which can be obtained via fulvene intermediates. In one embodiment, the cyclopentadiene ring is substituted with a trialkylsilyl moiety, which enables the further reaction with certain metal halides to form metal adducts. For example, the monoalkyl cyclopentadienes substituted with a trimethylsilyl group can be reacted with TiCl 4 to provide R*CpTiCl 3 complexes, wherein R* is a group of the formula n nwherein R 1 and R 2 are as defined herein.

专利号:US-5516884-A
优先权日:1994-03-09
标 题:Preparation of polycarbynes and diamond-like carbon materials made therefrom
发明人：BIANCONI PATRICIA A
权利人:PENN STATE RES FOUND
摘要:Synthesis and characterization of polycarbynes, a new class of carbon-based random network polymers. The network backbones of the polymers are composed of tetrahedrally hybridized carbon atoms, each bearing one substituent and linked via three carbon-carbon single bonds into a three-dimensional continuous random network backbone. Silicon, germanium, tin, lead, Group 13 through Group 16 elements, lanthanides, and Group 4 metals can be incorporated into the polymer backbone. The atomic-level carbon network backbone confers unusual properties on the polymers, including thermal decomposition to form diamond or diamond-like carbon.

专利号:US-4436838-A
优先权日:1982-09-29
标题:Process for preparing alkanols and esters from synthesis gas
发明人：LIN JIANG-JEN
权利人:TEXACO INC
摘要:This invention concerns a process for making alkanols and esters which comprises reacting a mixture of CO and H2 at a pressure of about 500 psig or greater and at a temperature of at least 150 DEG C. in the presence of a catalyst system comprising a ruthenium-containing compound, a second metal from Group IVB, VB, or VIB, consisting of a zirconium, titanium, vanadium or chromium-containing compound and a quaternary phosphonium salt, in the presence of an inert, oxygenated solvent.

专利号:EP-2554547-B1
优先权日:2011-08-03
标题 :Transition-metal catalyzed synthesis of diboranes(4)
发明人：BRAUNSCHWEIG HOLGER; Güthlein Frank
权利人:JULIUS MAXIMILIANS UNIVERSITÄT WÃœRZBURG

专利号:CN-116410224-A
优先权日:2023-06-05
标题 :A kind of synthesis technique of cyclopentadiene titanium trichloride

专利号:CN-116410224-B
优先权日:2023-06-05
标题:A kind of synthesis technology of cyclopentadiene titanium trichloride