CAS: 109537-55-5; Furfuryl2-Methyl-3-Furyldisulfide

该化合物是有机化合物,其独特结构包括一只呋喃环和一个二硫醚功能组.该化合物的特征是附于呋喃环的甲基组,有助于其芳香特性,而二硫醚联系则由于硫磺原子的存在而具有潜在的再活动性.松木动物的出现表明,它可能表现出有趣的电子特性,并可能参与各种化学反应,如电子替代或核细胞攻击.此外,含有呋喃和硫磺功能的化合物经常因其生物活动而加以研究,包括抗微生物和抗氧化特性.这种化合物的溶性性和稳定性可能因溶剂和环境条件而不同,因此在合成化学和药用化学环境中都具有相关性.

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65505-17-1 28588-75-2 61197-09-9

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合成工艺路线路线简述

    📜糠基硫醇,2-甲基-3-呋喃硫醇置于copper(II) Sulfate体系中,用 乙醚 用作溶剂,化学反应 0.58H,反应生成糠基 2-甲基-3-呋喃基二硫醚
    参考文献:Evaluation Of The Key Odorants In A Thermally Treated Solution Of Ribose And Cysteine By Aroma Extract Dilution Techniques
    标题:Evaluation Of The Key Odorants In A Thermally Treated Solution Of Ribose And Cysteine By Aroma Extract Dilution Techniques
    摘要:Application Of The Aroma Extract Dilution Analysis On A Solvent Extract Isolated From A Thermally Treated Solution (145 Degrees C; 20 Min) Of Cysteine/ribose Led To The Identification Of 2-Furfurylthiol,3-Mercapto-2-Pentanone,2-Methyl-3-Furanthiol,5-Acetyl-2,3-Dihydro-1,4-Thiazine,3-Mercapto-2-Butanone,And Bis(2-Methyl-3-Furyl) Disulfide Showing The Highest Flavor Dilution Factors Among The 29 Odor-Active Volatiles. Hrgc/olfactometry Of Decreasing Headspace Volumes Established Especially 2-Furfurylthiol And 2-Methyl-3-Furanthiol As Important Odorants And Revealed 2-Thenyl Mercaptan And Ethyl Mercaptan As Further Key Contributors To The Overall Roasty,Meatlike,Sulfury Odor Of The Model Mixture. 5-Acetyl-2,3-Dihydro-1,4-Thiazine,Identified For The First Time Among The Volatiles Of Maillard Model Reactions Or Foods,Exhibited An Intense Roasty,Popcorn-Like Odor At The Low Odor Threshold Of 0.06 Ng/l Of Air,Which Was Of The Same Order Of Magnitude As Those Reported In The Literature For The Roasty-Smelling Odorants 2-Acetyl-1-Pyrroline And 2-Acetyl-2-Thiazoline.
    Doi:10.1021/jf00056A042

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/bf00866569
    摘要:Golovnya RV, Misharina TA. Modern trends in the investigation of flavor components. Russian Chemical Bulletin. 1992 Jun;41(6):977–86. doi: 10.1007/bf00866569.
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