CAS: 94124-39-7; Tert-Butylmethoxyphenylsilylbromide
该化合物是一种多用途有机化合物,以其在合成有机化学中的作用著称. 它与各种有机溶剂非常相容,并且是有机硅烷合成的关键中间体,有机硅烷对各种应用,包括制药,材料科学和电子应用至关重要. 它的稳定性和回弹性使它成为化学家开发新材料和化合物的宝贵工具.
- 英文名称Tert-Butylmethoxyphenylsilylbromide
- 中文名称叔丁基甲氧苯基溴硅烷
- IUPAC名称bromo(tert-butyl)(methoxy)(phenyl)silane
- 其它别名Bromo(Tert-Butyl)(Methoxy)(Phenyl)Silane; Bromo-Tert-Butylmethoxyphenylsilane; Bromo-Tert-Butyl-Methoxy-Phenylsilane; Bromo-Tert-Butyl(Methoxy)Phenylsilane; Tert-Butylmethoxyphenylbromosilane; Tert-Butylm
- CAS编号94124-39-7
- MFCD编号:MFCD00043308
- EINECS号:620-727-2
- 分子式:C11H17BrOSi分子量:273.25
- 产品CID: 1987924
- 产品分类化学试剂 → 有机试剂 → 硅氧烷
物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS05;
注释: Corrosion - 危险类别皮肤腐蚀 类别1B
金属腐蚀物 类别1
严重眼损伤 类别1 - 警示词Danger(危险)
- 危险描述H314 |造成严重皮肤灼伤和眼损伤.
H290 |可能对金属造成腐蚀.
H318 |造成严重眼损伤. - 防范说明P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
- 危险等级8
- UN编号UN 3265 8/PG 2
- 危险品标志C
- 包装等级III
- 安全声明26-36/37/39-45
- 危险类别码34
- WGK Germany3
欧盟法规
C&L通报上下游产品
CAS号76358-47-9 叔丁基二苯基甲氧基硅烷合成工艺路线路线简述
📜叔丁基二苯基甲氧基硅烷置于溴体系中,用 1,2-二氯乙烷 作为反应溶剂,化学反应 16.0H,以65%的收率获得产物叔丁基甲氧苯基溴硅烷
参考文献:-Butylmethoxyphenylsilyl Ether-A New Selective,Stable Alcohol Protecting Group With Remarkable Lability To Fluoride.
标题:-Butylmethoxyphenylsilyl Ether-A New Selective,Stable Alcohol Protecting Group With Remarkable Lability To Fluoride.
摘要:
DOI:10.1016/s0040-4039(01)81501-X
海关参考信息
- 2902200000-苯
2905110000-甲醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-6242614-B1
优先权日:1999-05-28
标 题:Semi-synthesis of paclitaxel using dialkyldichlorosilanes
发明人：VEMISHETTI PURUSHOTHAM; GIBSON FRANCIS S; DILLON JOHN L
权利人:BRISTOL MYERS SQUIBB CO
摘要:A process for the synthesis of paclitaxel from 10-deacetylbaccatin-III which is protected at the 7-position with a dialkylalkoxysilyl protecting group having the formula —Si(R) 2 (OR′).
专利号:EP-1183250-A4
优先权日:1999-05-28
标 题 :HALF SYNTHESIS OF PACLITAXEL WITH THE HELP OF DIALKYLDICHLOROSILANES
专利号:EP-1183250-B1
优先权日:1999-05-28
标题:Semi-synthesis of paclitaxel using dialkyldichlorosilanes
专利号:WO-0073293-A1
优先权日:1999-05-28
标 题 :Semi-synthesis of paclitaxel using dialkyldichlorosilanes
专利号:EP-1183250-A1
优先权日:1999-05-28
标 题 :Semi-synthesis of paclitaxel using dialkyldichlorosilanes
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Bryostatins: The Asymmetric Synthesis Of The C1-C9And C17-C27Fragments作者:Jef De Brabander,Maurits Vandewalle
摘要:The Construction Of The Fragments C1-C9 3 And C17-C27, 4A Of The Bryostatins In A Enantioselective And Highly Diastereoselective Fashion Is Described. The Usefulness Of The "Chiron" Approach Is Illustrated With The Synthesis Of These Fragments From, Respectively, D-Pantolactone (6) And D-Isobutyl Lactate (23) As Chiral Templates.
合成参考文献
摘要:Skrydstrup, T., Science of Synthesis, (2002) 4, 273.
📝 需求与反馈
尽可能描述清楚需求与问题信息
