CAS: 4411-89-6; 2-Phenylbut-2-Enal

该化合物是一种有机化合物,其结构特征是其结构,其结构特征是丁基脊柱,与第二个碳相连的苯基组;该化合物被归类为一种不饱和的aldhyde,意指它既含有甲型苯乙烯功能组,也含有甲型碳和乙型碳的双联;它一般看起来像一种无色的黄色淡色液体,具有独特的芳香味. 2-phenyl-2-butenal,因其活动性而闻名,特别是由于碳基组的电光学性质,它可以参与各种化学反应,包括Michael的添加和凝聚反应;该化合物对有机合成感兴趣,并可用于生产香气,调味剂和其他有机化合物合成的中间体;其特性,如沸点和溶解性,可以因环境条件和其他物质的存在而变化.

结构式图片

相似化合物

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合成工艺路线路线简述

    📜Buta-1,3-Dien-1-Ylbenzene置于乙醚,碘,Mercury(II) Oxide体系中,化学反应生成 α-亚乙基-苯乙醛
    参考文献:Deux,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1940,Vol. 211,P. 441
    标题:Deux,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1940,Vol. 211,P. 441

    海关参考信息

    专利信息


    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:WO-0125179-A1
    优先权日:1999-10-01
    标 题:Preparation of tetracyclic intermediates
    发明人:CHEN QING PING; WOODS ROSS ALEXANDER; ELLIOTT ROBYN LOUISE
    权利人:INST OF DRUG TECHNOLOGY AUSTRA; CHEN QING PING; WOODS ROSS ALEXANDER; ELLIOTT ROBYN LOUISE
    摘要:The invention provides a process for preparing deoxytetracyclic compounds of formula (I) useful in the synthesis of anthracyclines by the rearrangement of thiono ester derivatives followed by reduction, as well as intermediates useful therefor. In said formula, R is H or optionally protected OH.

    专利号:WO-2004096766-A1
    优先权日:2003-04-29
    标题 :A method of indole synthesis
    发明人:BANWELL MARTIN GERHARDT; LUPTON DAVID WILLIAM
    权利人:UNIV AUSTRALIAN; BANWELL MARTIN GERHARDT; LUPTON DAVID WILLIAM
    摘要:The present invention relates to methods for the synthesis of indoles. In particular, the invention relates to the coupling of an a-haloenone or a-haloenal with an ortho-halonitroarene to form an ortho-(enone)nitroarene or ortho-(enal)nitroarene. Reductive cyclization of an ortho-(enone)nitroarene or ortho-(enal)nitroarene affords access to indole compounds.

    专利号:US-7012142-B2
    优先权日:2000-10-27
    标 题:Process for preparation of bicyclic and polycyclic molecules
    发明人:PERLMUTTER PATRICK; ROSE MARK; THIENTHONG NEERANAT
    权利人:UNIV MONASH
    摘要:The present application is directed to a method of synthesis of a bicyclic or polycyclic compound of formula I or formula II: n n nin which E, G, Y, n, m, R, R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 are as defined.

    专利号:WO-2005019236-A1
    优先权日:2003-08-21
    标题:Novel sulfenamide oxides
    发明人:VON ITZSTEIN LAURENCE MARK; DAVIS CHRISTOPHER BONNER; THOMSON ROBIN JOY
    权利人:UNIV GRIFFITH; VON ITZSTEIN LAURENCE MARK; DAVIS CHRISTOPHER BONNER; THOMSON ROBIN JOY
    摘要:Sulfenamide oxide compounds of general formula (I) are disclosed wherein A, R1, R2, X1, X1’, X2, X2’, X3, X3’, X4, X4’, X5 and X5’ define a variety of variables and wherein q is 0 or 1 and p is 1 or 2. The compounds disclosed in the examples are galactofuranosyl and glucofuranosyl sulfenamide oxide compounds wherein the variable A is oxygen. Methods of synthesis of compounds of general formula (I), pharmaceutical compositions containing them and methods of using them to treat patients suffering a microbial infection are also disclosed.

    专利号:WO-2005019237-A1
    优先权日:2003-08-21
    标题:Novel sulfenamides
    发明人:VON ITZSTEIN LAURENCE MARK; DAVIS CHRISTOPHER BONNER; THOMSON ROBIN JOY; HARTNELL REGAN DAVID; MADGE PAUL DAVID ORR
    权利人:UNIV GRIFFITH; VON ITZSTEIN LAURENCE MARK; DAVIS CHRISTOPHER BONNER; THOMSON ROBIN JOY; HARTNELL REGAN DAVID; MADGE PAUL DAVID ORR
    摘要:Sulfenamide compounds of general formula (I) are disclosed wherein A, R1, R2, X1, X1’, X2, X2’, X3, X3’, X4, X4’, X5 and X5’ define a variety of variables and q is 0 or 1. The compounds of the examples are galactofuranosyl and arabinofuranosyl compounds wherein the variable A is oxygen. Methods for the synthesis of compounds of general formula (I), pharmaceutical compositions them and methods of using them to treat patients suffering a microbial infection are also disclosed.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Vinylethylene Carbonates As α,β-Unsaturated Aldehyde Surrogates For Regioselective [3 + 3] Cycloaddition
    作者:Yi Xu,Lu Chen,Yu-Wen Yang,Zhiqiang Zhang,Weibo Yang |发布日期:2019.9.6
    摘要:Operationally Simple [3 + 3] Cycloaddition Of Vinylethylene Carbonates With Triazinanes. Interestingly, We Could Also Use This Method For A [3 + 3] Oxidative Cycloaddition, Which Allows The Facile Synthesis Of Polysubstituted Terphenyls Under Mild Conditions. Mechanistic Studies Suggest That Vinylethylene Carbonates Could Generate α,β-Unsaturated Aldehydes As 3-Carbon Synthons For Cycloaddition Via A Combination

    合成参考文献


    摘要:The Good Scents Company Information System
    摘要:Methot, J. L.; Roush, W. R., Science of Synthesis, (2009) 42, 474.
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