CAS: 21370-71-8; Trans-1-Decalone

该化合物是属于delcalin家族的双环切酮,其特征是其反爆环状结构.该化合物被广泛用作有机合成的中间体,特别是在香气,药品和特殊化学品的生产中.其僵硬的反形结构与其晶体对口相比,具有更大的稳定性和不同的反动性,因此对于立体选择性变异很有价值.跨1-12光线在普通有机溶剂中表现出低挥发性和高溶性,便利其在实验室和工业环境中的处理.其明确界定的结构也作为研究合成化学中的环状和反应机制的示范系统.

英文名称Trans-1-Decalone
中文名称反-1-十酮
IUPAC名称(4aR,8aS)-octahydronaphthalen-1(2H)-one
其它别名1-Decalone, Trans-; Octahydro-1(2H)-Naphthalenone; Octahydro-2H-Naphthalen-1-One; Trans-Alpha-Decalone; Trans-Bicyclo[4.4.0]Decan-2-One; Trans-Decalone; Trans-Decalone-1; Trans-1-Decalone
CAS编号21370-71-8
MFCD编号:MFCD00064175
EINECS号:244-352-5
FDA UNII编号:22P3A7D875
分子式:C10H16O分子量:152.24
产品CID: 1102332
产品分类化学试剂 → 有机试剂 → 脂肪酮（含烯醇）

相似结构搜索
产品信息参考;;;;
InChIKey: AFEFRXAPJRCTOW-BDAKNGLRSA-N
InChI=1S/C10H16O/c11-10-7-3-5-8-4-1-2-6-9(8)10/h8-9H,1-7H2/t8-,9+/m1/s1
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

MSDS等安全信息

UN编号NONH for all modes of transport
安全声明24/25
WGK Germany3

上下游产品

合成工艺路线路线简述

493-02-7 = 21370-71-8 + 825-51-4 + 529-32-8 + 55693-34-0 + 16021-08-2
反应条件:1.1 Reagents: Trifluoroacetic Acid,2,2′-Bipyridine,Oxygen Catalysts: Hexakis[μ-(Acetato-Ko:Ko′)]-μ3-Oxotris(Pyridine)Triiron Solvents: Pyridine
标题:Selective Oxidation Of Saturated Hydrocarbons Using An Electrochemical Modification Of The Gif System
作者:Balavoine,Gilbert; Et Al
参考文献:Tetrahedron Letters 日期:1986 卷标:27(25) 页码:2849-52

海关参考信息

2912110000-甲醛
2912120000-乙醛
2914110000-丙酮
2914120000-丁酮
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-6600029-B1
优先权日:1995-12-19
标题:Metabolic engineering of polyhydroxyalkanoate monomer synthases
发明人：SHERMAN DAVID H; WILLIAMS MARK D; XUE YONGQUAN
权利人:UNIV MINNESOTA
摘要:A novel pathway for the synthesis of polyhydroxyalkanoate is provided. A method of synthesizing a recombinant polyhydroxyalkanoate monomer synthase is also provided. These recombinant polyhydroxyalknoate synthases are derived from multifunctional fatty acid synthases or polyketide synthases and generate hydroxyacyl acids capable of polymerization by a polyhydroxyalknoate synthase.

专利号:US-2003194784-A1
优先权日:2001-04-17
标题:DNA encoding methymycin and pikromycin
发明人：SHERMAN DAVID H; LIU HUNG-WEN; XUE YONGQUAN; ZHAO LISHAN
摘要:A novel pathway for the synthesis of polyhydroxyalkanoates is provided. A method of synthesizing a recombinant polyhydroxyalkanoate monomer synthase is also provided. These recombinant polyhydroxyalkanoate synthases are derived from multifunctional fatty acid synthases or polyketide synthases and generate hydroxyacyl acids capable of polymerization by a polyhydroxyalkanoate synthase. Also provided is a biosynthetic gene cluster for methymycin and pikomycin as well as a biosynthetic gene cluster for desosamine.

专利号:US-6265202-B1
优先权日:1998-06-26
标题 :DNA encoding methymycin and pikromycin
发明人：SHERMAN DAVID H; LIU HUNG-WEN; XUE YONGQUAN; ZHAO LISHAN
权利人:UNIV MINNESOTA
摘要:A novel pathway for the synthesis of polyhydroxyalkanoates is provided. A method of synthesizing a recombinant polyhydroxyalkanoate monomer synthase is also provided. These recombinant polyhydroxyalkanoate synthases are derived from multifunctional fatty acid synthases or polyketide synthases and generate hydroxyacyl acids capable of polymerization by a polyhydroxyalkanoate synthase. Also provided is a biosynthetic gene cluster for methymycin and pikomycin as well as a biosynthetic gene cluster for desosamine.