2-正己酰噻吩 反应生成2-正己基噻吩 参考文献:Buu-Hoi Et Al.,Journal Of The Chemical Society,1955,P. 1581,1583 标题:Buu-Hoi Et Al.,Journal Of The Chemical Society,1955,P. 1581,1583
专利号:US-11078073-B2 优先权日:2015-02-23 标 题:Self-processing synthesis of hybrid nanostructures 发明人:YERUSHALMI ROIE; PALTIEL YOSSEF; PINCHAS-HAZUT ORI; WAICHMAN SHARON; ZIV AMIR; YOCHELIS SHIRA 权利人:YISSUM RES DEV CO OF HEBREW UNIV JERUSALEM LTD 摘要:Provided is a self-processing synthesis of hybrid nanostructures, novel nanostructures and uses thereof in the construction of electronic and optoelectronic devices.
专利号:US-2008086013-A1 优先权日:2006-06-15 标 题:Carbometallation of alkynes and improved synthesis of uniquinones 发明人:LIPSHUTZ BRUCE H 权利人:UNIV CALIFORNIA 摘要:Methods for the carbometallation of alkynes are presented. Those are useful for the synthesis of CoQ 10 and other ubiquinones as well as for the synthesis of ubiquinol analogs.
专利号:WO-2015109451-A1 优先权日:2014-01-22 标 题 :Synthesis of compounds containing 8-oxa-3-azabicyclo (3.2.1)octane ring 发明人:LI PENG; DECAMPO FLORYAN; SHI FENG; CUI XINJIANG; YUAN HANGKONG 权利人:RHODIA OPERATIONS; LANZHOU INSTITUTION OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCE 摘要:The present invention mainly pertains to catalytic processes for the direct amination of 2, -bis(hydroxymethyl) tetrahydrofuran to obtain compounds containing the 8-oxa-3-azabicyclo (3.2.1) octane ring, in the presence of: a homogenous catalyst which is a complex comprising at least one element selected from the group consisting of Iridium or Ruthenium and at least one donor ligand, or a heterogeneous catalyst comprising at least one Group 8-11 transition metal element and one poor metal element in the p-block of the period table.
专利号:US-2013045416-A1 优先权日:2011-08-15 标题 :Gold micro- and nanotubes, their synthesis and use 发明人:SEFEROS DWIGHT S; BRIDGES COLIN; DICARMINE PAUL 权利人:UNIV TORONTO; SEFEROS DWIGHT S; BRIDGES COLIN; DICARMINE PAUL 摘要:Synthesis of gold microtubes and nanotubes suspendable in solution is presented. The synthesis is accomplished using an AAO template route, wherein a polymer tube is used as a sacrificial core. The synthesis produces hollow structures that consist of only gold. These nanostructures exhibit two SPR modes, which correspond to both the transverse and longitudinal modes. The mode assignment was confirmed by measuring SPR behavior as both aligned arrays and in solution. The performance of gold nanotubes as refractive index detectors was quantified and determined to be more sensitive than analogous solid nanorods prepared under identical conditions, and are among the most sensitive nanostructured plasmon sensors to date. Due to their intense and sensitive resonances in the NIR spectrum, these solution-suspendable nanoparticles have potential to be used as in vitro or in vivo sensors.
专利号:US-9000170-B2 优先权日:2012-03-19 标 题:Process for the preparation of tetracarboxynaphthalenediimide compounds disubstituted with heteroaryl groups 发明人:SCHIMPERNA GIULIANA; PELLEGRINO ANDREA; CHIABERGE STEFANO; BIANCHI GABRIELE 权利人:ENI SPA 摘要:A process for the preparation of a tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups having general formula (I), comprising the reaction of at least one disubstituted N,N′-dialkyl-1,5,8-tetracarboxynaphthalenediimide with at least one heteroaryl compound. Said tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups can be advantageously used as monomer in the synthesis of semiconductor polymers which can be advantageously used in the construction of organic field effect transistors (OFET) or of organic thin film transistors (OTFT).
专利号:US-12291639-B2 优先权日:2017-12-14 标题:Electrically conducting poly(pyrazoles) 发明人:MARTIN BRETT D; GILES IAN D; NACIRI JAWAD; CHARLES PAUL T; TRAMMELL SCOTT A; DESCHAMPS JEFFREY R; DEPRIEST JEFFREY C 权利人:US GOV SEC NAVY 摘要:This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.
[参考文献]: Ozawa H, Et Al. Ruthenium Sensitizers With A Hexylthiophene-Modified Terpyridine Ligand For Dye-Sensitized Solar Cells: Synthesis, Photo- And Electrochemical Properties, And Adsorption Behavior To The Tio2 Surface.Acs Appl Mater Interfaces. 2015 Feb 11;7(5):3152-61.
合成参考文献
摘要:Harris, P. A., Science of Synthesis: Knowledge Updates, (2024) 1, 68. 摘要:Patil, N. T.; Bera, P.; Paroi, B., Science of Synthesis: Hypervalent Halogens in Organic Synthesis, (2025) .