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Midecamycin acetate, Miokamycin, 1532-RB, MOM, Mosil, Miocamycin, Miocamen, Macroral

醋酸麦迪霉素 麦迪霉素 Chemical Name: 9,3''-Di-O-acetylmidecamycin
CAS No. 55881-07-7, 35457-80-8 (free base)
项目整合开发状态: Launched-1985
项目研究机构: Meiji Seika (Originator), Bellon (Licensee), Menarini (Licensee), Merck KGaA (Licensee), Zambeletti (Licensee)
合成路线:The acetylation of midecamycin (SF-837 antibiotic) (I) with acetic anhydride in hot pyridine (1,3),or with acetyl chloride and Molecular Sieve 4A-30 in dichloromethane (2,4) gives 9,2',3''-triacetylmidecamycin (II),which is partially deacetylated in hot aqueous methanol.
📌 参考资料/链接:
参考文献标题:9,3'',4''-Triacylester of the antibiotic SF-837 M1 substance and the production thereof
文献作者:Inouye,S.; Omoto,S.; Iwamatsu,K.; Tsuruoka,T.; Niida,T.; Kawasaki,T.(Meiji Seika Kaisha,Ltd.)
参考来源:BE 0832813; DE 2537375; FR 2282903; GB 1520145; JP 55012040B; US 4017607

📄 详细内容


合成路线:The acetylation of midecamycin (SF-837 antibiotic) (I) with acetic anhydride in hot pyridine (1,3),or with acetyl chloride and Molecular Sieve 4A-30 in dichloromethane (2,4) gives 9,2',3''-triacetylmidecamycin (II),which is partially deacetylated in hot aqueous methanol.

参考文献标题:Process for the production of a 9,3''-diacyl derivative of a macrolide antibiotic
文献作者:Nakamura,T.; Nakabayashi,S.; Fukatsu,S.; Seki,S.(Meiji Seika Kaisha,Ltd.)
参考来源:DE 2835547; FR 2400524; GB 2003145; JP 54032493; US 4188480


合成路线:The acetylation of midecamycin (SF-837 antibiotic) (I) with acetic anhydride in hot pyridine (1,3),or with acetyl chloride and Molecular Sieve 4A-30 in dichloromethane (2,4) gives 9,2',3''-triacetylmidecamycin (II),which is partially deacetylated in hot aqueous methanol.

参考文献标题:Miokamycin
文献作者:Castar,J.; Serradell,M.N.; Blancafort,P.
参考来源:Drugs Fut 1983,8(9),790


合成路线:The acetylation of midecamycin (SF-837 antibiotic) (I) with acetic anhydride in hot pyridine (1,3),or with acetyl chloride and Molecular Sieve 4A-30 in dichloromethane (2,4) gives 9,2',3''-triacetylmidecamycin (II),which is partially deacetylated in hot aqueous methanol.

参考文献标题:Modifications of a macrolide antibiotic midecamycin (SH-837).I.Synthesis and structure of 9,3''-diacetylmidecamycin
文献作者:Inouye,S.; Iwamatsu,K.; Niida,T.; Omoto,S.
参考来源:J Antibiot 1976,24(5),536-548


合成路线:The acetylation of midecamycin (SF-837 antibiotic) (I) with acetic anhydride in hot pyridine (1,3),or with acetyl chloride and Molecular Sieve 4A-30 in dichloromethane (2,4) gives 9,2',3''-triacetylmidecamycin (II),which is partially deacetylated in hot aqueous methanol.
参考文献标题:A convenient method for the preparation of the acylated macrolide antibiotic midecamycin using molecular sieves and acylchloride
文献作者:Fukatsu,S.; Seki,S.; Nakamura,T.; Niida,T.
参考来源:Chem Lett 1978,(11),1293-96


产品链接: CAS No. 55881-07-7››

产品链接: CAS No.35457-80-8››