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Ricainide, Indecainide, LY-135837, Decabid

英地卡胺Chemical Name: 9-[3-[(1-Methylethyl)amino]propyl]-9H-fluorene-9-carboxamide; 9-[3-(Isopropylamino)propyl]fluorene-9-carboxamide
CAS No. 74517-78-5, 73681-12-6 (monoHCl)
项目整合开发状态: Withdrawn-1996
项目研究机构: Lilly (Originator)
合成路线:The condensation of 9-cyanofluorene (I) with 3-(dimethylamino)propyl chloride (II) by means of sodium amide in refluxing THF gives 9-[3-(dimethyl amino)propyl]-9-cyanofluorene (III),which is hydrolyzed partially with hot sulfuric acid water.
📌 参考资料/链接:
参考文献标题:Neoglucoproteins,their preparation and use
文献作者:Wiegand,H.; Bosslet,S.; Bosslet,K.; Sedlacek,K.(Behringwerke AG)
参考来源:AU 8944368; EP 0368131

📄 详细内容


合成路线:The condensation of 9-cyanofluorene (I) with 3-(dimethylamino)propyl chloride (II) by means of sodium amide in refluxing THF gives 9-[3-(dimethyl amino)propyl]-9-cyanofluorene (III),which is hydrolyzed partially with hot sulfuric acid water.

参考文献标题:Antiarrhythmic method
文献作者:Lacefield,W.B.; Simon,R.L.(Eli Lilly and Company)
参考来源:US 4197313


合成路线:The condensation of fluorene-9-carboxamide (IV) with acrylonitrile (V) by means of benzyltrimethylammonium hydroxide (VI) in hot dioxane gives 9-carbamoyl-9-(2-cyanoethyl)fluorene (VII),which is then hydrogenated and condensed with isopropylamine (VIII) and H2 over PtO2 with the same isopropylamine (VIII) as solvent.

参考文献标题:9-Carbamoyl-9-(2-cyanoethyl)fluorenes
文献作者:Lavagnino,E.R.; Pike,A.J.; Campbell,J.B.(Eli Lilly and Company)
参考来源:DD 158395; EP 0038676; GB 2074161; JP 1125363; US 4282170


合成路线:The condensation of 9-cyanofluorene (I) with 3-(dimethylamino)propyl chloride (II) by means of sodium amide in refluxing THF gives 9-[3-(dimethyl amino)propyl]-9-cyanofluorene (III),which is hydrolyzed partially with hot sulfuric acid water.

合成路线:The condensation of fluorene-9-carboxamide (IV) with acrylonitrile (V) by means of benzyltrimethylammonium hydroxide (VI) in hot dioxane gives 9-carbamoyl-9-(2-cyanoethyl)fluorene (VII),which is then hydrogenated and condensed with isopropylamine (VIII) and H2 over PtO2 with the same isopropylamine (VIII) as solvent.
参考文献标题:Indecainide
文献作者:Serradell,M.N.; Sneddon,J.; Castar,J.
参考来源:Drugs Fut 1985,10(2),121


产品链接: CAS No. 74517-78-5››

产品链接: CAS No.73681-12-6››