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Eterobarb, RMI-16238, DMNP, EX 12-095, Antilon

依特比妥Chemical Name: 1,3-Bis(methoxymethyl)-5-ethyl-5-phenyl-2,4,6-(1H,3H,5H)-pyrimidinetrione; 1,3-Bis(methoxymethyl)-5-ethyl-5-phenylbarbituric acid; 1,3-Bis(methoxymethyl)phenobarbital
CAS No. 27511-99-5
项目整合开发状态: Phase III
项目研究机构: Colgate Palmolive (Originator), MacroChem (Licensee)
合成路线:By reaction of sodium phenobarbital (I) with 2 mols of methyl chloromethyl ether (A) in DMF.It can also be obtained by reaction of phenobarbital (II),2 mols of NaH,LiH,KH,LiOH or t-BuOK and 2 moles of methyl chloromethyl ether (A) in DMF.
📌 参考资料/链接:
参考文献标题:Krampflende Verbindungen
文献作者:Samour,C.M.; et al.(The Kendall Company)
参考来源:DE 1939787; ES 370220; FR 2015091; GB 1276386

📄 详细内容


合成路线:By reaction of sodium phenobarbital (I) with 2 mols of methyl chloromethyl ether (A) in DMF.It can also be obtained by reaction of phenobarbital (II),2 mols of NaH,LiH,KH,LiOH or t-BuOK and 2 moles of methyl chloromethyl ether (A) in DMF.

参考文献标题:Verfahren zur Herstellung von 5,5-disubstituierten N,N'-Dialkyloxyalkyl- oder N,N'-Dibenzyloxyalkylverbindugen der Barbitus鋟re
文献作者:Vida,J.A.(The Kendall Company)
参考来源:DE 2005108; FR 2033950; GB 1276387


合成路线:By reaction of sodium phenobarbital (I) with 2 mols of methyl chloromethyl ether (A) in DMF.It can also be obtained by reaction of phenobarbital (II),2 mols of NaH,LiH,KH,LiOH or t-BuOK and 2 moles of methyl chloromethyl ether (A) in DMF.

参考文献标题:Eterobarb
文献作者:Castar,J.; Playle,A.C.
参考来源:Drugs Fut 1976,1(6),286


合成路线:By reaction of sodium phenobarbital (I) with 2 mols of methyl chloromethyl ether (A) in DMF.It can also be obtained by reaction of phenobarbital (II),2 mols of NaH,LiH,KH,LiOH or t-BuOK and 2 moles of methyl chloromethyl ether (A) in DMF.
参考文献标题:Anticonvulsants.1.Alkoxymethyl derivatives of barbiturates and diphenylhydantoin
文献作者:Samour,C.M.; et al.
参考来源:J Med Chem 1971,14(3),187


产品链接: CAS No. 27511-99-5››