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Diaziquone, CI-904, NSC-182986, AZQ

亚丝醌Chemical Name: Diethyl 2,5-bis(1-aziridinyl)-3,6-dioxo-1,4-cyclohexadiene-1,4-dicarbamate; 2,5-Diaziridinyl-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone; [2,5-Bis(1-aziridinyl)-3,6-dioxo-1,4-cyclohexanediene-1,4-diyl]biscarbamic acid diethyl ester
CAS No. 57998-68-2
项目整合开发状态: Phase III
项目研究机构: National Cancer Institute (Originator), MedImmune Oncology (Licensee)
合成路线:The reaction of chloranil (I) with ethyl carbamate (II) by means of Na in dry benzene gives 2,5-dichloro-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (III),which is then condensed with aziridine (IV) by means of triethylamine in THF.
📌 参考资料/链接:
参考文献标题:Aziridinyl quinone anti-transplanted tumor agents
文献作者:Driscoll,J.S.; et al.(US Department of Health & Human Services)
参考来源:US 4146622

📄 详细内容


合成路线:The reaction of chloranil (I) with ethyl carbamate (II) by means of Na in dry benzene gives 2,5-dichloro-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (III),which is then condensed with aziridine (IV) by means of triethylamine in THF.

参考文献标题:AZQ
文献作者:Cabanillas,F.; Blancafort,P.; Serradell,M.N.; Castar,J.
参考来源:Drugs Fut 1981,6(6),338


合成路线:The reaction of chloranil (I) with ethyl carbamate (II) by means of Na in dry benzene gives 2,5-dichloro-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (III),which is then condensed with aziridine (IV) by means of triethylamine in THF.

参考文献标题:Potential central nervous system antitumor agents.Azirinylbenzoquinones.1
文献作者:Kahn,A.H.; Driscoll,J.S.
参考来源:J Med Chem 1976,19(2),313-317


合成路线:The reaction of chloranil (I) with ethyl carbamate (II) by means of Na in dry benzene gives 2,5-dichloro-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (III),which is then condensed with aziridine (IV) by means of triethylamine in THF.

参考文献标题:
文献作者:Zubrod,C.G.; Rall,D.P.
参考来源:Anu Rev Pharmacol 1962,2109


合成路线:The reaction of chloranil (I) with ethyl carbamate (II) by means of Na in dry benzene gives 2,5-dichloro-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (III),which is then condensed with aziridine (IV) by means of triethylamine in THF.
参考文献标题:Structure-antitumor activity relationships among quinone derivatives
文献作者:Driscoll,J.S.; et al.
参考来源:Cancer Chemother Rep 1974,4(2),1


产品链接: CAS No. 57998-68-2››