REN-1189, CPI-1189

4-乙酰氨基-N-(叔-丁基)苯酰胺Chemical Name: 4-Acetamido-N-(tert-butyl)benzamide
CAS No. 183619-38-7
项目整合开发状态: Phase II
项目研究机构: Renovis (Proprietary), Centaur (Originator)
合成路线:4-Nitrobenzoyl chloride (I) was condensed with tert-butyl amine to give amide (II).The nitro group of (II) was then reduced to aniline (III) by transfer hydrogenation with hydrazine and Pd/C.Finally,acylation of (III) with acetyl chloride provided the title acetamide.
📌 参考资料/链接:
参考文献标题:Benzamides for neurodegenerative disorder treatment
文献作者:Garland,W.A.; Wilcox,A.L.; Paylor,R.E.; Flitter,W.D.(Centaur Pharmaceuticals,Inc.)
参考来源:US 5955506; WO 9631462

📄 详细内容


合成路线:4-Nitrobenzoyl chloride (I) was condensed with tert-butyl amine to give amide (II).The nitro group of (II) was then reduced to aniline (III) by transfer hydrogenation with hydrazine and Pd/C.Finally,acylation of (III) with acetyl chloride provided the title acetamide.

参考文献标题:Benzamide therapeutics for the treatment of inflammatory bowel disease
文献作者:Flitter,W.D.; Irwin,I.; Garland,W.A.(Centaur Pharmaceuticals,Inc.)
参考来源:WO 9959569


合成路线:4-Nitrobenzoyl chloride (I) was condensed with tert-butyl amine to give amide (II).The nitro group of (II) was then reduced to aniline (III) by transfer hydrogenation with hydrazine and Pd/C.Finally,acylation of (III) with acetyl chloride provided the title acetamide.

参考文献标题:Benzamide treatment of dementia,associated with AIDS virus (HIV-1) infection
文献作者:Garland,W.(Centaur Pharmaceuticals,Inc.)
参考来源:WO 9738684


合成路线:4-Nitrobenzoyl chloride (I) was condensed with tert-butyl amine to give amide (II).The nitro group of (II) was then reduced to aniline (III) by transfer hydrogenation with hydrazine and Pd/C.Finally,acylation of (III) with acetyl chloride provided the title acetamide.
参考文献标题:CPI-1189
文献作者:Sorbera,L.A.; Castar,J.; Leeson,P.A.
参考来源:Drugs Fut 2001,26(7),647


产品链接: CAS No. 183619-38-7››