Properties: Crystallizes in various forms with different mps, but [according to Taylor, J. Chem. Soc.
1952, 4832] on recrystn from methanol all of these forms yield the one melting at 232-234°. [a]D15 +44.5 ± 2° (c = 1.1683 in methanol); [a]D23 +49.5° (methanol). uv max: 218, 277.5 nm (log e 4.2, 1.83). Sol in water, methanol, chloroform.
Melting point: melting at 232-234°
Optical Rotation: [a]D15 +44.5 ± 2° (c = 1.1683 in methanol); [a]D23 +49.5° (methanol)
Absorption maximum: uv max: 218, 277.5 nm (log e 4.2, 1.83)
Derivative Type: Diacetate
Properties: Crystals, mp 254-256° (corr). [a]D22 +24.2° (chloroform).
Melting point: mp 254-256° (corr)
Optical Rotation: [a]D22 +24.2° (chloroform)
Derivative Type: Dibenzoate
Properties: Cryst powder from methanol, mp 189° (Taylor, loc. cit.); mp 187-191° (micro-block, Rothrock et al., loc. cit.); [a]D23 +30.7 ± 1° (c = 1.301 in acetone). Sol in acetone; slightly sol in methanol.
Melting point: mp 189° (Taylor, loc. cit.); mp 187-191° (micro-block, Rothrock et al., loc. cit.)
Optical Rotation: [a]D23 +30.7 ± 1° (c = 1.301 in acetone)
Status: This monograph has been retired and is no longer subject to revision or update.
产品链接: 22146-03-8››