Fuscin CAS Registry Number: 83-85-2 暗褐菌素
CAS Name: 9,10-Dihydro-5-hydroxy-4,8,8-trimethyl-2H,4H-benzo[1,2-b:4,3-c']dipyran-2,6(8H)-dione
Percent Composition: C 65.21%, H 5.84%, O 28.96%
📌 参考资料/链接：
Literature References: Antibacterial pigment produced by the fungus Oidiodendron fuscom Robak: Michael, Biochem. J. 42, XL; 43, 528 (1948). Derivatives and degradation products: Birkinshaw et al., ibid. 48, 66 (1951). Structure and synthesis: Birch, Chem. Ind. (London) 1955, 682; Barton, Hendrickson, J. Chem. Soc. 1956, 1028. Alternate synthesis: Pyuskyulev et al., Tetrahedron 29, 2849 (1973). Biosynthesis: Birch, Ciba Found. Symp. Quinones Electron Transp. 1960, 233; Birch et al., J. Chem. Soc. 1965, 1231.
📄 详细内容
Properties: Orange-colored, diamond-shaped plates from alc, mp 230°. uv max: 355, 283 nm (e 27,600; 1000). Practically insol in water, petr ether. Sol in chloroform, acetone, ethyl acetate, acetic acid, ether, benzene. Slightly sol in cold ethanol, more sol in hot ethanol. Dissolves in aq solns of alkali hydroxides and pyridine with an intense purple color. Easily reduced by hydrosulfite or other reducing agents to the colorless dihydrofuscin, C15H18O5, mp 206°, which is also found in the metabolic soln from the fungus grown on Czapek-Dox medium.
Melting point: mp 230°; mp 206°
Absorption maximum: uv max: 355, 283 nm (e 27,600; 1000)
Status: This monograph has been retired and is no longer subject to revision or update.
产品链接: 83-85-2››