Pseudopelletierine CAS Registry Number: 552-70-5 9-甲基-9-氮杂双环[3.3.1]壬-3-酮
CAS Name: 9-Methyl-9-azabicyclo[3.3.1]nonan-3-one
Additional Names: 9-methyl-3-granatanone; pseudopunicine
Percent Composition: C 70.55%, H 9.87%, N 9.14%, O 10.44%
📌 参考资料/链接：
Literature References: In root bark of Punica granatum L., Punicaceae. Extraction procedure: Hess, Eichel, Ber. 50, 380, 1391, 1395 (1917); ibid. 52, 1012 (1919). Synthesis under physiological conditions from calcium acetonedicarboxylate, glutardialdehyde, and methylamine: Menzies, Robinson, J. Chem. Soc. 1924, 2163; cf. Schöpf, Angew. Chem. 50, 779, 797 (1937). Alternate syntheses: Cope et al., Org. Synth. 37, 73 (1957); Robinson, Hunt, J. Pharm. Pharmacol. 22, 29S (1970); Bottini, Gal, J. Org. Chem. 36, 1718 (1971). Conformation: Chen, LeFevre, J. Chem. Soc. B 1966, 539.
📄 详细内容
Properties: Orthorhombic prisms from petr ether, mp 54°; bp 246°. Volatile. Strong base. One gram dissolves in about 2.5 ml water, 10 ml ether. Freely sol in alcohol and chloroform; sparingly sol in petr ether.
Melting point: mp 54°
Boiling point: bp 246°
Derivative Type: Dihydrate
Properties: Plates from water.
Derivative Type: Hydrochloride
Percent Composition: C 56.99%, H 8.50%, N 7.38%, O 8.43%, Cl 18.69%
Properties: Rhombohedra. One gram dissolves in about 1 ml water.
Derivative Type: Sulfate tetrahydrate
Percent Composition: C 45.36%, H 8.46%, N 5.88%, O 33.57%, S 6.73%
Properties: Crystals, sol in water.
产品链接: 552-70-5››