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Indanazoline hydrochloride, Farial

1H-咪唑-2-胺,N-(2,3-二氢-1H-坼-4-基)-4,5-二氢,盐酸盐(1:1) 茚唑啉 Chemical Name: N-(2,3-Dihydro-1H-inden-4-yl)-4,5-dihydro-1H-imidazol-2-amine hydrochloride
CAS No. 56601-85-5, 40507-78-6 (free base)
项目整合开发状态: Launched
项目研究机构: Abbott (Originator)
合成路线: 4-Amiomoindan (I) is reacted with benzoylisothiocyanate (II) to give the benzoylthiourea (III),which after hydrolysis of 4-indanyltiourea (IV) is methylated with iodomethane to (V).The free base (VI) is cyclized with ethyldiamine (A) and p-toluenesulfonic acid to indanazoline

合成路线:By reacting 1-acetyl-2-imidazolidinone (VII) with 4-aminoindan (I) and POCl3 at 50 C 1-acetylindanazolidine (VIII) is synthesized,which gives indanazoline by hydrolysis
📌 参考资料/链接:
参考文献标题:Indanazoline Hydrochloride
文献作者:Unterhalt,B.
参考来源:Drugs Fut 1981,6(7),417

📄 详细内容


合成路线: 4-Amiomoindan (I) is reacted with benzoylisothiocyanate (II) to give the benzoylthiourea (III),which after hydrolysis of 4-indanyltiourea (IV) is methylated with iodomethane to (V).The free base (VI) is cyclized with ethyldiamine (A) and p-toluenesulfonic acid to indanazoline

合成路线:By reacting 1-acetyl-2-imidazolidinone (VII) with 4-aminoindan (I) and POCl3 at 50 C 1-acetylindanazolidine (VIII) is synthesized,which gives indanazoline by hydrolysis

参考文献标题:BRCA mutations and risk of prostate cancer in ashkenazi jews
文献作者:Kirchhoff,T.; Kauff,N.D.; Mitra,N.; et al.
参考来源:Arzneim-Forsch Drug Res 1980,30(9),1733


合成路线: 4-Amiomoindan (I) is reacted with benzoylisothiocyanate (II) to give the benzoylthiourea (III),which after hydrolysis of 4-indanyltiourea (IV) is methylated with iodomethane to (V).The free base (VI) is cyclized with ethyldiamine (A) and p-toluenesulfonic acid to indanazoline

参考文献标题:
文献作者:May,H.J.; Berg,A.(Nordmark-Werke GmbH)
参考来源:BE 786499; CA 967162; DE 2136325; FR 2146430; GB 1346037; JP 7319575; JP 7918260; NL 7209138; SA 7204747; SU 571502; US 3882229


合成路线:By reacting 1-acetyl-2-imidazolidinone (VII) with 4-aminoindan (I) and POCl3 at 50 C 1-acetylindanazolidine (VIII) is synthesized,which gives indanazoline by hydrolysis
参考文献标题:
文献作者:May,H.J.; Koening,H.(BASF AG)
参考来源:DE 2652004; FR 2370736; NL 7712149


产品链接: CAS No. 56601-85-5››

产品链接: CAS No.40507-78-6››