Alkasar-18, NOAC

1-[(2R,3S,4S,5R)-3,4-二羟基-5-(羟基甲基)四氢呋喃-2-基]-4-(十八烷基氨基)嘧啶-2-酮Chemical Name: 1-(beta-D-Arabinofuranosyl)-4-(octadecylamino)-2(1H)-pyrimidinone; N4-Octadecyl-1-beta-D-arabinofuranosylcytosine
CAS No. 158233-67-1
项目整合开发状态: Phase I/II
项目研究机构: Universit鋞 T黚ingen (Originator)
合成路线:NOAC (II) is prepared from octadecylamine and 4-(1,2,4-triazol-1-yl)-1-beta-D-2',3',5'-tri-O-acetylarabinofuranosyl) pyrimidine-2(1H)-one (I) in dioxane.Yields are > 95%.Purity by HPLC is > 97.5%.Solvent residues (methanol,chloroform) are < 0.3%.NOAC has been analyzed by the following spectroscopic methods: H-1 NMR,C-13 NMR,C-13 DEPT NMR,IR and MS.The spectroscopic data of all methods used is consistent with the structure of NOAC.
📌 参考资料/链接:
参考文献标题:Treatment of L1210 murine leukemias with liposome-incorporated N4-hexadecyl-1-beta-D-arabinofuranosylcytosine
文献作者:Schwendener,R.A.; Schott,H.
参考来源:Int J Cancer 1992,51(3),466-9

📄 详细内容


合成路线:NOAC (II) is prepared from octadecylamine and 4-(1,2,4-triazol-1-yl)-1-beta-D-2',3',5'-tri-O-acetylarabinofuranosyl) pyrimidine-2(1H)-one (I) in dioxane.Yields are > 95%.Purity by HPLC is > 97.5%.Solvent residues (methanol,chloroform) are < 0.3%.NOAC has been analyzed by the following spectroscopic methods: H-1 NMR,C-13 NMR,C-13 DEPT NMR,IR and MS.The spectroscopic data of all methods used is consistent with the structure of NOAC.

参考文献标题:Alkasar-18
文献作者:Schwendener,R.A.; Horber,D.H.; Ottiger,C.; Rentsch,K.; Fiebig,H.H.; Schott,H.
参考来源:Drugs Fut 1995,20(1),11


合成路线:NOAC (II) is prepared from octadecylamine and 4-(1,2,4-triazol-1-yl)-1-beta-D-2',3',5'-tri-O-acetylarabinofuranosyl) pyrimidine-2(1H)-one (I) in dioxane.Yields are > 95%.Purity by HPLC is > 97.5%.Solvent residues (methanol,chloroform) are < 0.3%.NOAC has been analyzed by the following spectroscopic methods: H-1 NMR,C-13 NMR,C-13 DEPT NMR,IR and MS.The spectroscopic data of all methods used is consistent with the structure of NOAC.

参考文献标题:Synthesis of 4-alkylcytosine nucleosides and evaluation of cytostatic activity in the L1210 murine leukemia
文献作者:Schott,H.; H鋟ssler,M.P.; Schwendener,R.A.
参考来源:Liebigs Ann Chem 1994,5(5),465-70


合成路线:NOAC (II) is prepared from octadecylamine and 4-(1,2,4-triazol-1-yl)-1-beta-D-2',3',5'-tri-O-acetylarabinofuranosyl) pyrimidine-2(1H)-one (I) in dioxane.Yields are > 95%.Purity by HPLC is > 97.5%.Solvent residues (methanol,chloroform) are < 0.3%.NOAC has been analyzed by the following spectroscopic methods: H-1 NMR,C-13 NMR,C-13 DEPT NMR,IR and MS.The spectroscopic data of all methods used is consistent with the structure of NOAC.
参考文献标题:4-(1,2,4-Triazol-1-yl)-1-beta-D-2',3',5'-tri-O-acetylarabinofuranosyl) pyrimidine-2-(1H)-ones.Valuable intermediates in the synthesis of derivatives of 1-(beta-D-arabinofuranosyl)cytosine (Ara-C)
文献作者:Divakar,K.J.; Reese,C.B.
参考来源:J Chem Soc - Perkins Trans I 1982,1171-6


产品链接: CAS No. 158233-67-1››