新产品编号:808911

Chemical Name: Sulfamic acid 4-nonanoylphenyl ester
CAS No. 319922-34-4
项目整合开发状态: Biological Testing
项目研究机构: Kingston University (Originator)
合成路线:Friedel-Crafts acylation of phenol (I) with nonanoyl chloride (II) in the presence of AlCl3 afforded ketone (III).Aminosulfonyl chloride (V) was prepared by decarboxylation of chlorosulfonyl isocyanate (IV) upon treatment with formic acid.Finally,condensation of the sodium phenolate of (III) with aminosulfonyl chloride (V) furnished the title sulfamate.
📌 参考资料/链接:
参考文献标题:Sulphamate cpds.
文献作者:Ahmed,S.(Kingston University)
参考来源:WO 0104086

📄 详细内容


合成路线:Friedel-Crafts acylation of phenol (I) with nonanoyl chloride (II) in the presence of AlCl3 afforded ketone (III).Aminosulfonyl chloride (V) was prepared by decarboxylation of chlorosulfonyl isocyanate (IV) upon treatment with formic acid.Finally,condensation of the sodium phenolate of (III) with aminosulfonyl chloride (V) furnished the title sulfamate.

参考文献标题:Novel inhibitors of the enzyme estrone sulfatase (ES)
文献作者:Ahmed,S.; James,K.; Owen,C.P.; Patel,C.K.; Patel,M.
参考来源:Bioorg Med Chem Lett 2001,11(6),841


合成路线:Friedel-Crafts acylation of phenol (I) with nonanoyl chloride (II) in the presence of AlCl3 afforded ketone (III).Aminosulfonyl chloride (V) was prepared by decarboxylation of chlorosulfonyl isocyanate (IV) upon treatment with formic acid.Finally,condensation of the sodium phenolate of (III) with aminosulfonyl chloride (V) furnished the title sulfamate.
参考文献标题:Synthesis and biochemical evaluation of novel and potent inhibitors of the enzyme oestrone sulphatase (ES)
文献作者:Ahmed,S.; James,K.; Owen,C.P.; Patel,C.K.
参考来源:J Steroid Biochem Mol Biol 2002,80(4-5),419