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NSC-716976, BNP-7787, Tavocept, Mesna disulfide, Dimesna

Chemical Name: 2,2'-Dithiobis(ethanesulfonic acid) disodium salt
CAS No. 16208-51-8
项目整合开发状态: Phase III
项目研究机构: BioNumerik (Originator), Takeda (Marketer), Baxter Oncology (Licensee), Grelan (Licensee)
合成路线:Oxidation of an aqueous solution of sodium 2-mercaptoethanesulfonate (I) with I2 provided the title disulfide.In a related procedure,addition of sodium hydrosulfide to the sodium salt of vinylsulfonic acid (II) gave intermediate (III) which,without isolation,was oxidized with O2 at 60 C under pressure.
📌 参考资料/链接:
参考文献标题:Compsn.of cisplatin in combination with 2,2'-dithio-bis(ethanesulfonate) (dimesna)
文献作者:Haridas,K.; Reddy,D.G.; Murali,D.; Hausheer,F.H.(BioNumerik Pharmaceuticals,Inc.)
参考来源:WO 9614852

📄 详细内容


合成路线:Oxidation of an aqueous solution of sodium 2-mercaptoethanesulfonate (I) with I2 provided the title disulfide.In a related procedure,addition of sodium hydrosulfide to the sodium salt of vinylsulfonic acid (II) gave intermediate (III) which,without isolation,was oxidized with O2 at 60 C under pressure.

参考文献标题:Reducing toxic effects of carboplatin using dithioethers
文献作者:Hausheer,F.H.; Seetharamulu,P.; Murali,D.; Reddy,D.G.; Haridas,K.(BioNumerik Pharmaceuticals,Inc.)
参考来源:WO 9811898


合成路线:Oxidation of an aqueous solution of sodium 2-mercaptoethanesulfonate (I) with I2 provided the title disulfide.In a related procedure,addition of sodium hydrosulfide to the sodium salt of vinylsulfonic acid (II) gave intermediate (III) which,without isolation,was oxidized with O2 at 60 C under pressure.

参考文献标题:Process for making mesna,dimesna and derivs.thereof
文献作者:Haridas,K.(BioNumerik Pharmaceuticals,Inc.)
参考来源:US 5808140; WO 9814426


合成路线:Oxidation of an aqueous solution of sodium 2-mercaptoethanesulfonate (I) with I2 provided the title disulfide.In a related procedure,addition of sodium hydrosulfide to the sodium salt of vinylsulfonic acid (II) gave intermediate (III) which,without isolation,was oxidized with O2 at 60 C under pressure.
参考文献标题:Coviracil NDA accepted for filing by FDA
文献作者:
参考来源:J Org Chem 1961,261330-1331


产品链接: CAS No. 16208-51-8››