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Camostat mesilate, Camostat mesylate, FOY-305, Foipan

甲磺酸卡莫司他 卡莫司他 Chemical Name: p-Guanidinobenzoic acid,ester with (p-hydroxyphenyl)acetic acid,ester with N,N-dimethylglycolamide mesylate
CAS No. 59721-29-8, 59721-28-7 (free base)
项目整合开发状态: Launched-1985
项目研究机构: Ono (Originator), Il Sung (Licensee)
合成路线:The reaction of p-hydrophenylacetic acid (I) with N,N-dimethylbromoacetamide (II) by means of triethylamine in reftuxing acetonitrile gives N,N-dimethylcarbamoylmethyl-p-hydroxyphenylacetate (III),which is then condensed with p-guanidinobenzoyl chloride (IV) [obtained from the corresponding acid p-guanidinobenzoic acid (V) and thionyl chloride] in pyridine.
📌 参考资料/链接:
参考文献标题:Guanidinobenzoic acid derivatives
文献作者:Fujii,S.; Uegai,Y.; Watanabe,T.; Kayama,N.(Ono Pharmaceutical Co.,Ltd.)
参考来源:DE 2548886; FR 2289181; GB 1472700; JP 76054530; US 4021472

📄 详细内容


合成路线:The reaction of p-hydrophenylacetic acid (I) with N,N-dimethylbromoacetamide (II) by means of triethylamine in reftuxing acetonitrile gives N,N-dimethylcarbamoylmethyl-p-hydroxyphenylacetate (III),which is then condensed with p-guanidinobenzoyl chloride (IV) [obtained from the corresponding acid p-guanidinobenzoic acid (V) and thionyl chloride] in pyridine.

参考文献标题:Guanidinobenzoic acid derivatives and antiplasmin agents and remedies for pancreas diseases containing the said guanidinobensolc acid derivatives
文献作者:Fujii,S.; et al.(Ono Pharmaceutical Co.,Ltd.)
参考来源:JP 52089640


合成路线:By reaction of N,N-dimethylcarbamoylmethyl-p-(p-aminobenzoyloxy)phenylacetate (VI) with cyanamide (VII).

参考文献标题:Preparation of guanidinobenzoic acid derivatives
文献作者:Fujii,S.; et al.(Ono Pharmaceutical Co.,Ltd.)
参考来源:JP 54052052


合成路线:The reaction of p-hydrophenylacetic acid (I) with N,N-dimethylbromoacetamide (II) by means of triethylamine in reftuxing acetonitrile gives N,N-dimethylcarbamoylmethyl-p-hydroxyphenylacetate (III),which is then condensed with p-guanidinobenzoyl chloride (IV) [obtained from the corresponding acid p-guanidinobenzoic acid (V) and thionyl chloride] in pyridine.

合成路线:By reaction of N,N-dimethylcarbamoylmethyl-p-(p-aminobenzoyloxy)phenylacetate (VI) with cyanamide (VII).
参考文献标题:Camostat Mesylate
文献作者:Castar,J.; Serradell,M.N.; Hashimoto,K.
参考来源:Drugs Fut 1985,10(11),897


产品链接: CAS No. 59721-29-8››

产品链接: CAS No.59721-28-7››