Piroximone, MDL-19205

匹罗昔酮Chemical Name: 4-Ethyl-1,3-dihydro-5-(4-pyridinylcarbonyl)-2H-imidazol-2-one
CAS No. 84490-12-0
项目整合开发状态: Phase III
项目研究机构: Aventis Pharma (Originator)
合成路线:The acid chloride (II) of isonicotinic acid is prepared by reaction of oxalyl chloride (A) with the potassium salt of isonicotinic acid (I).The acylation of 1,3-dihydro-4-ethyl-2H-imidazol-2-one (III) with acid chloride (II) under Friedel-Crafts' conditions gives 1,3-dihydro-4-isonicotinoyl-5-ethyl-2H-imidazol-2-one.
📌 参考资料/链接:
参考文献标题:Piroximone
文献作者:Mannhold,R.
参考来源:Drugs Fut 1984,9(12),905

📄 详细内容


合成路线:The acid chloride (II) of isonicotinic acid is prepared by reaction of oxalyl chloride (A) with the potassium salt of isonicotinic acid (I).The acylation of 1,3-dihydro-4-ethyl-2H-imidazol-2-one (III) with acid chloride (II) under Friedel-Crafts' conditions gives 1,3-dihydro-4-isonicotinoyl-5-ethyl-2H-imidazol-2-one.

参考文献标题:4-Pyridylimidazolones and method of use
文献作者:Schnettler,R.A.; Dage,R.C.; Grisar,J.M.; Palopoli,F.P.
参考来源:EP 0059948; ES 8305352; ES 8402827; GB 2096600; US 4405628


合成路线:The acid chloride (II) of isonicotinic acid is prepared by reaction of oxalyl chloride (A) with the potassium salt of isonicotinic acid (I).The acylation of 1,3-dihydro-4-ethyl-2H-imidazol-2-one (III) with acid chloride (II) under Friedel-Crafts' conditions gives 1,3-dihydro-4-isonicotinoyl-5-ethyl-2H-imidazol-2-one.
参考文献标题:4-Aroyl-1,3-dihydro-2H-imidazol-2-ones,a new class of cardiotonic agents.Effect of 4-Pyridoyl substituents and related compounds
文献作者:Dage,R.C.; Schnettler,R.A.; Palopoli,F.P.
参考来源:186th ACS Natl Meet (Aug.28 - Sept.2,Washington,D.C.) 1983,Abst MEDI-84


产品链接: CAS No. 84490-12-0››