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Enocitabine, NSC-239336, BHAC, Sunrabin

依诺他滨Chemical Name: 1-(beta-D-Arabinofuranosyl)-N4-docosanoylcytosine; N4-Behenoyl-1-beta-D-arabinofuranosylcytosine
CAS No. 55726-47-1
项目整合开发状态: Launched-1984
项目研究机构: Asahi Kasei (Originator)
合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.
📌 参考资料/链接:
参考文献标题:Process for preparing N4-acylcytarabines
文献作者:Ishida,T.; et al.(Asahi Chemical Industry Co.,Ltd.)
参考来源:JP 52007974

📄 详细内容


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:Behenoyl Ara-C
文献作者:Serradell,M.N.; Cabanillas,F.; Castar,J.; Blancafort,P.
参考来源:Drugs Fut 1980,5(12),603


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:N4-Acylarabinonucleosides and the preparation thereof
文献作者:Ishida,T.; et al.
参考来源:DE 426304; FR 2231388; GB 1449708; JP 50018482


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:N4-Acylarabinonucleosides apparatus for handling articles
文献作者:Ishida,T.; et al.
参考来源:DE 2461862; FR 2342070; JP 51019777


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7632573


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7648679


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with docosanoyl anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with docosanoyl anhydride (II) as before to give N4-docosanoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7626884


产品链接: CAS No. 55726-47-1››