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Palmitoyl cytarabine, Palmitoyl Ara-C

N(4)-棕榈酰阿糖胞苷Chemical Name: N4-Palmitoyl-1-beta-D-arabinofuranosylcytosine; N4-Hexadecanoyl-1-beta-D-arabinofuranosylcytosine; N-(1-beta-D-Arabinofuranosyl-1,2-dihydro-2-oxo-4-pyrimidinyl)hexadecanamide
CAS No. 55726-45-9
项目整合开发状态: Phase III
项目研究机构: Asahi Kasei (Originator)
合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.
📌 参考资料/链接:
参考文献标题:N4-Acylarabinonucleosides and the preparation thereof
文献作者:Ishida,T.; et al.(Asahi Chemical Industry Co.,Ltd.)
参考来源:DE 2426304

📄 详细内容


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:N4-Acylarabinonucleosides
文献作者:Ishida,T.; et al.(Asahi Chemical Industry Co.,Ltd.)
参考来源:DE 2461862


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:Palmitoyl/Stearoyl Ara-C
文献作者:Cabanillas,F.; Castar,J.
参考来源:Drugs Fut 1980,5(12),617


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7707974


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7632573


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7648679


合成路线:This compound can be obtained in two different ways:1) By condensation of 1-beta-D-arabinofuranosylcytosine (I) with palmitic anhydride (II) in hot dioxane.2) By acylation of cytidine (III) with palmitic anhydride (II) in hot dioxane to yield N4-palmitoylcytidine (IV),which is then isomerized by treatment with POCl3 in ethyl acetate.

参考文献标题:
文献作者:Ishida,T.; et al.
参考来源:JP 7626884


产品链接: CAS No. 55726-45-9››