AGZ-1067, AGI-1067

4-(2,6-二-叔丁基-4-(2-(3,5-二-叔丁基-4-羟基苯基硫代)丙烷-2-基硫代)苯氧基)-4-氧代丁酸Chemical Name: Succinic acid 2,6-di-tert-butyl-4-[1-(3,5-di-tert-butyl-4-hydroxyphenylsulfanyl)-1-methylethylsulfanyl]phenyl monoester
CAS No. 216167-82-7
项目整合开发状态: Phase III
项目研究机构: AtheroGenics (Originator)
合成路线:Esterification of probucol (I) with succinic anhydride (II) in the presence of NaH afforded the title monosuccinate ester,which was separated from the unreacted probucol (I) and the corresponding disuccinate ester by column chromatography.Esterification of (I) was also reported in the presence of other bases,such as potassium tert-butoxide,KOH,DMAP and DABCO.
📌 参考资料/链接:
参考文献标题:Cpds.and methods for the inhibition of the expression of VCAM-1
文献作者:Medford,R.M.; Meng,C.Q.; Hoong,L.K.; Somers,P.K.(AtheroGenics,Inc.)
参考来源:JP 2002503227; US 6147250; WO 9851662

📄 详细内容


合成路线:Esterification of probucol (I) with succinic anhydride (II) in the presence of NaH afforded the title monosuccinate ester,which was separated from the unreacted probucol (I) and the corresponding disuccinate ester by column chromatography.Esterification of (I) was also reported in the presence of other bases,such as potassium tert-butoxide,KOH,DMAP and DABCO.

参考文献标题:Process for preparing probucol derivs.
文献作者:Jass,P.A.
参考来源:US 6323359


合成路线:Esterification of probucol (I) with succinic anhydride (II) in the presence of NaH afforded the title monosuccinate ester,which was separated from the unreacted probucol (I) and the corresponding disuccinate ester by column chromatography.Esterification of (I) was also reported in the presence of other bases,such as potassium tert-butoxide,KOH,DMAP and DABCO.

参考文献标题:Novel phenolic antioxidants as multifunctional inhibitors of inducible VCAM-1 expression for use in atherosclerosis
文献作者:Meng,C.Q.; Somers,P.K.; Rachita,C.L.; Holt,L.A.; Hoong,L.K.; Zehng,X.S.; Simpson,J.E.; Hill,R.R.; Olliff,L.K.; Kunsch,C.; Sundell,C.L.; Parthasarathy,S.; Saxena,U.; Sikorski,J.A.; Wasserman,M.A.
参考来源:Bioorg Med Chem Lett 2002,12(18),2545


合成路线:Esterification of probucol (I) with succinic anhydride (II) in the presence of NaH afforded the title monosuccinate ester,which was separated from the unreacted probucol (I) and the corresponding disuccinate ester by column chromatography.Esterification of (I) was also reported in the presence of other bases,such as potassium tert-butoxide,KOH,DMAP and DABCO.
参考文献标题:AGI-1067
文献作者:Sorbera,L.A.; Castar,J.
参考来源:Drugs Fut 2003,28(5),421


产品链接: CAS No. 216167-82-7››