网站主页>>>项目整合精选>>>项目整合精选>>>Phenicin CAS Registry Number: 128-68-7 (3Z)-3-(2,3-二羟基-4-甲基-6-氧代-1-环己-2,4-二烯亚基)-6-甲基环己-5-烯-1,2,4-三酮

Phenicin CAS Registry Number: 128-68-7 (3Z)-3-(2,3-二羟基-4-甲基-6-氧代-1-环己-2,4-二烯亚基)-6-甲基环己-5-烯-1,2,4-三酮


CAS Name: 2,2'-Dihydroxy-4,4'-dimethyl[bi-1,4-cyclohexadien-1-yl]-3,3',6,6'-tetrone
Additional Names: 3,3'-dihydroxy-5,5'-dimethyl-2,2'-bi-p-benzoquinone; phoenicin
Percent Composition: C 61.32%, H 3.68%, O 35.01%
📌 参考资料/链接:
Literature References: Fungal pigment produced by Penicillium phoeniceum and P. rubrum: Friedheim, Helv. Chim. Acta 21, 1464 (1938); Charollais et al., Arch. Sci. 16, 474 (1963). Synthesis: Posternak et al., Helv. Chim. Acta 26, 2031 (1943); Musso, Beecken, Ber. 92, 1416 (1959); J. Kalamar et al., Helv. Chim. Acta 57, 2368 (1974). Biosynthesis: E. Steiner et al., ibid. 2377.

📄 详细内容


Properties: Yellowish-brown crystals from alc, mp 230-231°. uv max (chloroform): 268, 406 nm (log e 4.52, 3.36). Sparingly sol in water; freely sol in chloroform, acetic acid, hot alcohol. Very acidic solns are yellow, turning red at pH 1.6-3.6 and violet at pH 4.9-6.
Melting point: mp 230-231°
Absorption maximum: uv max (chloroform): 268, 406 nm (log e 4.52, 3.36)
产品链接: 128-68-7››